排序方式: 共有2条查询结果,搜索用时 5 毫秒
1
1.
C.V.?Cristea C.?MoinetEmail author M.?JITARU M.?Darabantu 《Journal of Applied Electrochemistry》2005,35(9):845-849
Hydroxylamines electrogenerated from (1S,2S)-2-amino-1-(4-nitrophenyl)-propane-1,3-diol derivatives (derivatives of p-nitrophenylserinol) are unstable in methanol–acetate buffer and practically stable in acetonitrile–aqueous acetate buffer. This latter medium was used to carry out subsequent reactions in situ involving the triacetylated p-hydroxylaminophenylserinol and various reagents. An azoxy compound was the major product isolated after reaction with maleic or phthalic anhydrides. In contrast, a benzoxazine dione was normally obtained with phthaloyl dichloride and a N-sulphonylated hydroxylamine was produced with p-toluenesulphonyl chloride. 相似文献
2.
C.?V.?Cristea C.?MoinetEmail author M.?Jitaru I.?C.?Popescu 《Journal of Applied Electrochemistry》2005,35(9):851-855
Nitroso compounds were electrogenerated from (1S, 2S)-2-amino-1-(4-nitrophenyl)-propane-1,3-diol derivatives (derivatives of p-nitrophenylserinol) in a “redox” flow cell equipped with two consecutive porous electrodes of opposite polarities. In spite. of the relative instability in methanol-acetate buffer of the hydroxylamine intermediates produced at the first porous electrode (cathode), the nitroso derivatives were prepared in good yields at the second one (anode). A coupling reaction between some nitroso derivatives and p-toluenesulphinic acid led to N-sulphonylphenylhydroxylamines. 相似文献
1