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排序方式: 共有542条查询结果,搜索用时 16 毫秒
1.
本文提出用尿素作为pⅡ调节剂,加快硫酸亚铁单液法调剖剂中亚铁离子在地层温度下的沉淀,增大沉淀率,提高封堵效能。岩芯流动试验结果表明,15%FeSO4.7II 2O/5%尿素调剖剂体系的封堵能力比不含尿素的体系增大近一倍。 相似文献
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针对尿素合成塔的腐蚀问题,详细介绍了从投产使用到现在该设备的腐蚀现状.并从不同角度进行详细分析,提出了解决问题的办法及日常运行中应注意的问题. 相似文献
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The crystal structure of urea-polyethylene complex in the hexagonal form, obtained by one of our preparation methods, is analysed by X-ray power diffractometry. In this analysis, the fixed molecular parameters of urea are used, and three models with respect to rotational disorder of the guest polyethylene molecule are assumed. It is shown that the host lattice structure constructed by urea molecules is essentially the same as that of urea-n-paraffin complex. Effects of the disorder structure of the guest on X-ray scattering of the complex are presented. However, there is a difficulty in identifying the disorder structure by X-ray analysis. With the aid of a potential energy calculation between the hexagonal urea tunnel and the guest molecule, a rotational disorder model is preferred. 相似文献
5.
Catherine J. Watson 《Nutrient Cycling in Agroecosystems》1990,24(1):1-10
Urea can be an inefficient N source due to rapid hydrolysis by soil urease leading to NH3 volatilization. The current study investigated the effect of the urease inhibitor phenylphosphorodiamidate (PPD) incorporated at two concentrations (0.5% and 1% w/w) within the fertilizer granule on NH3 volatilization from surface applied urea. The daily rates of NH3 loss from 20 soils of widely differing properties from Northern Ireland were measured over 14 days using ventilated enclosures under simulated spring conditions. Cumulative loss rates were calculated and fitted to a logistic model from which total NH3 loss (Amax) and the time to maximum rate of loss (Tmax) were determined. Stepwise multiple linear regression analysis related the effectiveness of PPD in reducing NH3 volatilization from urea to soil properties.The total cumulative loss of ammonia from unamended urea varied from 0.37 to 29.2% depending on soil type. Ammonia volatilization appeared to be greatest on a soil with a high pH (R2 = 0.65), a low titratable acidity (TA) (R2 = 0.63) and a soil that was drying out (R2 = 0.50). Soil pH was negatively correlated with TA (r = –0.826, P < 0.001) suggesting that soils with a low TA may have received recent lime. Including cation exchange capacity (CEC) and % N as well as pH-KCl in the multiple linear regression equation explained 86% of the variance.The effectiveness of PPD in reducing Amax varied between 0% to 91% depending on soil type, the average over all 20 soils being 30 and 36% for 0.5% and 1% PPD respectively. The most important soil properties influencing the effectiveness of the urease inhibitor were soil pH-H2O and TA accounting for 33% and 29% of the variance respectively. PPD was less effective on a soil with a high pH and low TA. These were the soil conditions that led to high NH3 volatilization from unamended urea and may explain why PPD had limited success in reducing ammonia loss on these soils. Multiple linear regression analysis indicated that 75% of the variation in the % inhibition of NH3 loss by PPD could be significantly accounted for by pH-H2O, initial soil NO
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-N concentration, % moisture content and % moisture loss.The delay in Tmax by PPD ranged from 0.19 to 7.93 days, the average over all 20 soils being 2.5 and 2.8 days for 0.5% and 1% PPD respectively. TA, % moisture content, urease activity and CEC were soil properties that significantly explained 83% of the variation in the % delay in Tmax by PPD in multiple linear regression analysis. However, none of these soil properties were significant on their own. As urea hydrolysis occurs rapidly in soil, delaying Tmax under field conditions would increase the chance of rain falling to move the urea below the soil surface and reduce NH3 volatilization. A urease inhibitor should be more effective than PPD on soils with a high pH and low TA to be successful in reducing high NH3 losses. 相似文献
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机械松衬尿素合成塔衬里的修复白玲,唐联生,向均,江伟(成都化肥厂)关键词尿素合成塔,衬里,检修成都化肥厂尿素合成塔如图1所示,外筒采用多层15MnVgC板包扎而成,总厚度88mm,衬里是机械松衬6mm厚0Cr17Mn13Mo2N钢板,现在已使用10年... 相似文献
7.
先用尿素、甲醛合成二羟甲脲,然后在酸性介质下把二羟甲脲滴加在苯酚中反应合成尿素改性的热塑性酚醛树脂。研究了反应浑浊点和二羟甲脲的滴加速度,同时研究了二羟甲脲与苯酚的尿酚比与物料的出料温度、产品产率及树脂理化性能指标的关系。结果表明:(1)二羟甲脲滴加速度的合适范围是0.012-0.029mol/mol.min;(2)本树脂的出料温度为125℃以下;(3)产品收率,游离酚,软化点随尿比的增长而递增,凝胶速度变化不大。另介绍了这种树脂在酚醛模塑料中的应用。 相似文献
8.
弱酸性条件合成脲醛树脂工艺的探讨 总被引:1,自引:0,他引:1
探讨了在弱酸性条件下合成低甲醛释放量的脲醛树脂工艺的可能性。同时,对不同pH值条件下合成脲醛树脂的工艺及其性能进行了研究,并采用傅立叶红外光谱和化学方法对脲醛树脂的官能团进行了分析,同时定性分析了不同pH值条件下合成树脂的热学性能。研究表明在弱酸性条件下合成脲醛树脂的树脂性能和其胶合板的力学性能达到国家标准并且其胶合板甲醛释放量达到GB/T17657—1999中的E,级标准。弱酸性条件下合成脲醛树脂的工艺不仅能降低生产成本,还能生产性能优异的脲醛树脂胶黏剂。 相似文献
9.
耐水性木材用脲醛粘合剂的研究 总被引:6,自引:1,他引:6
研究了改进胶合板用脲醛粘合剂的耐水性的方法。针对脲醛粘合剂耐水性低的原因,提出在胶液中添加碱性物质——耐水添加剂,可显著改善胶合板的耐水性,几种添加剂并用,胶合板可达一级耐水板的水平。 相似文献
10.
介绍了在团粒法工艺的基础上,用尿素熔融尿液或尿素车间二段蒸发器的尿液进行喷浆造粒生产复合肥的改造方案、改造内容、改造效果和投资情况。 相似文献