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排序方式: 共有795条查询结果,搜索用时 15 毫秒
1.
Xian Suo Xili Cui Lifeng Yang Nan Xu Yuqi Huang Yi He Sheng Dai Huabin Xing 《Advanced materials (Deerfield Beach, Fla.)》2020,32(29):1907601
The design of highly stable and efficient porous materials is essential for developing breakthrough hydrocarbon separation methods based on physisorption to replace currently used energy-intensive distillation/absorption technologies. Efforts to develop advanced porous materials such as zeolites, coordination frameworks, and organic polymers have met with limited success. Here, a new class of ionic ultramicroporous polymers (IUPs) with high-density inorganic anions and narrowly distributed ultramicroporosity is reported, which are synthesized by a facile free-radical polymerization using branched and amphiphilic ionic compounds as reactive monomers. A covalent and ionic dual-crosslinking strategy is proposed to manipulate the pore structure of amorphous polymers at the ultramicroporous scale. The IUPs exhibit exceptional selectivity (286.1–474.4) for separating acetylene from ethylene along with high thermal and water stability, collaboratively demonstrated by gas adsorption isotherms and experimental breakthrough curves. Modeling studies unveil the specific binding sites for acetylene capture as well as the interconnected ultramicroporosity for size sieving. The porosity-engineering protocol used in this work can also be extended to the design of other ultramicroporous materials for the challenging separation of other key gas constituents. 相似文献
2.
乙炔在磁稳定床中的选择性加氢研究 总被引:1,自引:0,他引:1
制备了一种磁性Pd/Al2O3催化剂,采用磁稳定床考察了活性组分负载量、反应条件及CO浓度对乙炔加氢反应性能的影响。结果表明,当反应温度80℃、反应压力1.5MPa、空速9000h-1、磁场强度(H)25kA/m时,乙炔转化率为100%,乙烯选择性可达81%,具有优良的乙炔加氢活性和乙烯选择性,优于相同反应条件下的进口催化剂;250h稳定性实验结果表明,磁性Pd/Al2O3催化剂具有良好的初活性和乙烯选择性,催化剂性能稳定。 相似文献
3.
4.
柴油机针阀体的乙炔低压渗碳 总被引:2,自引:0,他引:2
乙炔低压渗碳可以有效地避免在真空渗碳过程中产生炭黑和焦油,同时由于乙炔具有较高的供碳能力,使这一技术尤其适用于针阀体这样的小直径深盲孔零件。 相似文献
5.
Pretreatment of acetylene cokes at 450 °C with a mixture of nitrogen, oxygen and water vapour creates a relatively large surface area and some initial microporosity, further developed by water activation at 800 °C. For the same degree of burn-off, but without pretreatment, large micropores (L > 2–3 nm) are obtained and the external surface area remains small. 相似文献
6.
Conducting composites of polythiophene (PTP) and polyfuran (PF) with acetylene black (AB) were prepared via chemical oxidative polymerization of thiophene and furan in a suspension of AB in CHCl3 at room temperature using anhydrous FeCl3 as the oxidant. Formation of PTP and PF and their subsequent incorporation in PTP–AB and PF–AB composite systems were confirmed by FTIR analysis. Scanning electron microscope analysis showed the presence of compact clusters of particles in both composites. Transmission electron micrographs of PTP–AB and PF–AB composites showed formation of globular polymer encapsulated AB particles with average diameters of the order of ~100 nm in both systems. Thermogravimetric analysis revealed that the overall thermal stability varied in the order: AB > PTP–AB > PTP and AB > PF–AB > PF. DC conductivity values for the PTP–AB and PF–AB composites were of the order of 10?2 and 10?3 S cm?1, respectively. Copyright © 2004 Society of Chemical Industry 相似文献
7.
余秀琴 《可编程控制器与工厂自动化(PLC FA)》2006,(10):56-58,55
本文介绍了应用西门子公司的LOG01可编程控制器(PLC)和艾墨森生产的变频器技术,使乙炔压缩机可以通过手动或者编程控制实现乙炔压缩机排气量的连续变化或分级输出,实现整机运行过程中的重要参数的实时监控和多项指标的极限报警,满足不同工况下的应用需求,节约能源和成本,提高了效益。 相似文献
8.
天然气等离子体法制乙炔 总被引:16,自引:4,他引:12
论述了天然气制乙炔的发展概况,并从技术经济角度比较了3种乙炔生产方法,其中天然气等离子体法在有效利用与节约能源、生产成本、安全性和环保等方面均优于部分氧化法和电石法,是一种很有前途的新方法。 相似文献
9.
Two conflicting structural models (platelet and fibril) have been proposed in the literature for pristine cis-poly(acetylene). The respective models have separate, distinct implications for the chemical, physical and electrical properties of the material, in particular, the cis-trans isomerization, doping and conduction mechanisms. Luttinger-type cis-poly(acetylene) was prepared and studied in the transmission electron microscope (TEM) by low-dose conventional imaging, in dark-field mode and by electron diffraction. Thin ‘films’ of the material were shown to consist of fibrillar nets, having fibrils of diameter 5–25 nm. Combined electron diffraction and dark-field observations in the TEM indicated the structural arrangement within the fibrils as that having polymer molecular chains aligned parallel to fibril axes. 相似文献
10.
The catalytic activities of WCI6Ph4Sn, MoCl5Ph4Sn and tetrabenzyltitanium were examined in the polymerization of acetylene. The structure, morphology and electrical conductivity of the doped and non doped polyacetylene were also studied. 相似文献