Formation process of zirconia nanotubes and porous structures and model of oxygen bubble growth

Preparation and growth mechanism of anodization of Ti and Al has been widely concerned for two decades, but the research on anodic ZrO₂ is relatively lacking. In this paper, anodic TiO₂ and ZrO₂ nanotubes were prepared in glycerol electrolyte containing 0.35 M NH₄F and 4 vol% H₂O under different anodizing voltages. We had successfully prepared the anodic ZrO₂ nanotubes (AZNTs) with a complete top and a “bulb” at the bottom under 60 V, and with the increase of the applied anodizing voltage, the “bulb” cavity also increased. However, under the same anodizing conditions, the surface of anodic TiO₂ nanotubes (ATNTs) is a cluster of nano-tip morphology, and the bottom of the ATNTs is a conventional hemisphere shape. In addition, both AZNTs and porous anodic zirconia (PAZ) were found to coexist in the anodic ZrO₂ layer prepared at 60 V. Here, we used the oxygen bubble model and ionic current and electronic current theories to analyze the reason of the special morphology. It is confirmed that the porous anodic oxides are actually evolved from nanotubes. In other words, the structure is essentially the same.     

自然循环窄矩形通道内过冷沸腾两相摩擦阻力特性

采用去离子水作为实验工质，在低压低流速自然循环工况下开展了单面加热可视化窄矩形通道内的过冷沸腾摩擦阻力特性实验研究。实验中测量了实验段内的压降数据，并通过高速摄影仪拍摄了窄矩形通道内的气液两相图像，提出了过冷沸腾条件下的两相摩擦压降的剥离计算方法。基于本实验中获得摩擦压降数据，对分别基于均相流模型和分液相模型的经典两相摩擦压降计算关系式进行了评估，实验结果表明：采用不同等效黏度计算方法的均相流模型计算结果比实验值明显偏小；而分相流模型中，Sun and Mishiba关系式和Tran关系式均能够较好地预测摩擦阻力，计算值与实验值的平均相对偏差在±15%以内。结合实验数据，以分相流模型方法为基础，考虑全液相Reynolds数、Martinelli参数和Laplace数的影响，获得了计算分液相折算系数的经验关系式，与实验数据符合较好, 平均相对误差在10%范围内。     

掺气减蚀保护作用的新概念

利用针式掺气流速仪测量原型和模型掺气浓度场、流速场，气泡尺寸及其概率分布的研究成果表明，原型水流韦伯数高，形成微小气泡的能力比模型强，气泡上浮慢，接近底部的小尺寸气泡概率及掺气浓度比模型大。初步研究认为：0.2mm或0.5mm以下的微小气泡在掺气减蚀中起着主要作用，可能只要很小掺气浓度即可达到掺气减蚀的效果。因此以小尺寸气泡的掺气浓度，作为判断掺气减蚀保护作用的指标将更为准确。     

气泡在粘弹性液体中溶解的研究进展

在发泡塑料的制造过程中，均相气体－聚合物体系的形成直接影响了制品的物理机械性能，因此了解气泡在粘弹性液体中的溶解机理成为必然。本文讲述了气泡在流体中塌陷行为的研究进展。对Rayleigh对低粘度牛顿流体，Foqer和Goddand在无线量线性Maxwell模型的粘弹性体，Tanasawa和Tang用oldroyd三常数粘弹模型等科学家的研究行为做了概述，总结出影响此过程的复杂的影响因素，并指出进一步的研究方向。     

Modeling for local dynamic behaviors of phenol biodegradation in bubble columns

A coupled three-dimensional (3-D) model, combining hydrodynamics with biochemical reactions, was developed to simulate the local transient flow patterns and the dynamic behaviors of cell growth and phenol biodegradation by yeast Candida tropicalis in the bubble-column bioreactor, using the computational fluid dynamic (CFD) method. In order to validate this proposed model effectively, the validation of the local hydrodynamic characteristics of the gas-mineral salt solution (gas-liquid) two-phase system, with the phenol concentration of 1200 mg/L, and with the absence of cells, was performed in a square-sectioned bubble column bioreactor using the LDA system and conductivity probe. Furthermore, the validation of phenol biodegradation behaviors by yeast Candida tropicalis at different initial concentrations of phenol and cell was also carried out in the above bubble-column bioreactor. The results indicated that the model simulations had a satisfying agreement with the experimental data. Finally, the local instantaneous flow and phenol biodegradation features including gas holdup, gas velocity, liquid velocity, cell concentration and phenol concentration inside the bioreactor were successfully predicted in different-scale bubble columns by the proposed model. © 2006 American Institute of Chemical Engineers AIChE J, 2006     

太钢不锈冷轧工程防腐蚀施工技术

防腐蚀施工工艺掌握的好坏，直接影响到工程投入生产后的使用寿命，为保证工程质量，以太钢不锈冷轧改造工程冷线防腐为例，对其常发生的质量通病进行认真分析，总结出一套行之有效的施工技术。     

Boiling: Size Distribution of Bubbles as Demanded by the Principle of Maximum Information

The principle of maximum informational entropy is used to find the probability density function for the departure radius of a bubble in boiling on a solid surface. A general relation is derived, which leads to particular expressions.     

Nucleate Pool Boiling of Pure Liquids and Binary Mixtures：PartI－Analytical Model for Boiling Heat Transfer of Pure Liquids on Smooth Tubes

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