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1.
Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts. 相似文献
2.
Animesh Chakrabarti Man Mohan Sharma 《Journal of the American Oil Chemists' Society》1992,69(12):1251-1253
Anhydrous esterification of myristic acid with propylene was carried out in the temperature range of 110–145°C and pressure
from 190–195 psig in the presence of Amberlyst-15 (cation exchange resin) and Filtrol-24 (acid-treated clay) as catalysts.
The product ester, isopropyl myristate finds use in cosmetic and topical medicinal preparations where good absorption through
the skin is desired. Filtrol-24 is the catalyst of choice, and the recommended operating temperature is 130°C with a pressure
of 190 psig. 相似文献
3.
马丽霞 《东北电力学院学报》2002,22(1):62-64
论述了某厂一级除盐系统阳床工艺特性及调整试验过程,对存在问题进行分析并改进,得到了实际运行最佳方式和参数,取得良好效果。 相似文献
4.
Katherine A. B. Logan Michael J. S. Floate 《Journal of the science of food and agriculture》1985,36(11):1084-1092
For 30 acid upland and hill soils, with initial pH from 3.5 to 5.8, and loss on ignition from 14% to 94%, cation exchange capacity varied with pH according to the relationship CEC = m pH+C, where m and C are characteristic of each soil. The slope m depended on loss on ignition (LOI), and is given by: m=Δ CEC/Δ=0.22 LOI+1.92. Because of these relationships, CEC measured at the natural pH of the soil (in 0.025 M MgSO4 solution) is more relevant to field conditions than a conventional measurement at pH7. An improved method for estimating lime requirement (LR) of these soils was developed, based on the relationship found between LR and the difference in CEC (ΔCEC) between that at the natural pH of the soil and that at the target pH of 5.5: LR=1.12 ΔCEC+1.48. Lime requirement can therefore also be estimated from loss on ignition using the earlier relationships, and is given by: LR=(0.25 LOI+2.15) Δ+1.48, where Δ is the difference between the natural pH (in 0.025 M MgSO4) and the target pH. Predictions based on this agreed well with results for a further 10 soils. 相似文献
5.
Achu is a thick porridge obtained by cooking and pounding taro (Colocasia esculenta) corms and cormels in a mortar. This study was undertaken with the objective of producing precooked taro flour that can be used in the preparation of achu. Taro slices were precooked to times of 0, 20, 45 and 90 min and dried in an air convection oven at varying temperatures of 50, 60, 70 or 80 °C before milling into flour which was then analysed for its water absorption capacity (WAC), water solubility index, emulsion activity and stability, bulk density, foam capacity and least gelation concentration (LGC). Achu made from the flours were equally analysed for their relative penetrometric index, bulk density and colour. The results showed that precooking induced significant (P<0.05) decrease in foam capacity, penetrometric index, and increase in LGC, emulsion stability and WAC. The drying temperature also induces significant reduction in emulsion capacity and stability, penetrometric index, and increase in LGC, WAC. Long precooking time (>45 min) and drying temperature (>60 °C) induced significant reduction of the in-vitro carbohydrate digestibility of taro achu. 相似文献
6.
Takaaki Wajima Tomoe Shimizu Yasuyuki Ikegami 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(6):921-927
BACKGROUND: This study aimed to investigate the synthesis of zeolites from paper sludge ash (PSA) with added diatomite to remove both NH4+ and PO43? for water purification. The PSA had low Si and significant Ca contents. Four types of diatomite: white (T‐W) and brown (T‐B) from deposits of marine origin in Takanosu, and white (S‐W) and gray (S‐G) from lacustrine deposits in Shonai, were added to NaOH solution to increase the Si content and thereby synthesize zeolites with high cation exchange capacity (CEC). RESULTS: The order of the amounts of Si extracted from the diatomite to the alkali solution was S‐W > T‐W = T‐B > S‐G, which correlates with the amorphous SiO2 content of diatomite. The original ash without addition of diatomite yielded hydroxysodalite with CEC of about 1.0 mmol g?1. For all samples, the addition of diatomite to the solution yielded zeolite‐P with a higher CEC, but the addition of excess Si inhibited the synthesis of zeolite‐P, and the CEC of the product was low. A product with high CEC including zeolite‐P was obtained in a solution with around 500 mmol L?1 of Si concentration, and had the ability to remove both NH4+ and PO43?. CONCLUSION: Diatomite has the potential for used as an additive for the synthesis of high CEC zeolite from PSA. The product with zeolite‐P exhibited relatively high CEC, capacity for NH4+ uptake, and the ability to remove PO43? by precipitation, which is preferable for water purification applications. Copyright © 2008 Society of Chemical Industry 相似文献
7.
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9.
Maltose long-chain fatty acid esters (MFAE), esterified at the 6 and 6′ position, were synthesized with stearic, palmitic,
myristic, and oleic groups. Synthesis yields were 15–20% based on initial maltose present, and structural confirmation was
obtained using plasma desorption mass spectrometry and nuclear magnetic resonance spectroscopy. These surfactants have surface
tensions in the range of 34–36 dyn/cm at their critical micelle concentrations (CMC) of approximately 10−5–10−6 mol/L. The increased chain lengths have a marked effect, reducing CMC values for MFAE by approximately three orders of magnitude
over similar carbohydrate-based dodecyl chain sources. Within chain lengths between 14 and 18 carbons, the rate of change
in CMC is significant and decreases with increasing chain length for MFAE. The melting points of MFAE are approximately 40°C,
and the heat capacities range from 1.6 to 1.9 J/g·K. These numbers are comparable to those of sucrose esters, indicating their
applicability in similar uses. However, because MFAE, unlike sucrose, possess an anomeric carbohydrate carbon position, these
surfactants maintain their reducing nature and are susceptible to further derivatization. They are also synthesized from renewable,
economical carbohydrates and lipids and may provide an excellent alternative to pertrochemical-derived products. 相似文献
10.
阳离子表面活性剂对HPAM溶液表观粘度的影响 总被引:1,自引:0,他引:1
研究了不同的阳离子表面活性剂对部分水解聚丙烯酰胺(HPAM)溶液中的表观粘度的影响。 相似文献