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1.
Preparation and Properties of Rare Earth Modified Carbon Black/Natural Rubber Composites 总被引:2,自引:2,他引:0
Lin Yaling Xiao Kongqing Zhang Anqiang Wang Lianshi 《中国稀土学报(英文版)》2005,23(6):720-720
The oxides Eu, Ho, Er and Dy were used to prepare the hydroxides of rare earth modified carbon black. Then natural rubber latex (NRL) was added into the reactor. The system reacted at 85 ℃ with stirring for 1 h to prepare powdered HAF-Ln(OH)3/NR composites. The effects of the kind and content of Ln on the particle size distribution of P [ NR/HAF-Ln (OH)3 ] and mechanical properties of its vulcanizate were studied respectively. It is found that rare earth can help to get the powder of the composite, the product particle with a diameter less than 0.9mm will be get when the composites containing the compound of Ho, Er and Dy with dosage of 1.0, 1.0, O. 5 percent, respectively. The adding of Ln can improve the tensile strength and tear strength of the vulcanizate effectively, what's more, Er and Dy can decrease the permanent set of vulcanizate significantly. The SEM studies shows that P[ NR/HAF-Dy (OH)3 ] vulcanizate shows superior mechanical properties that depend primarily on the absence of free carbon black, the fine dispersion of carbon black in the rubber matrix and better polymer-filler interaction. 相似文献
2.
The effect of FEF carbon black as filler on the thermal capacity c, diffusivity a, and thermal conductivity λ, of styrene butadiene rubber (SBR) composites in the temperature range 300–420 K was studied. The filler strongly increases the thermal diffusivity, whilst strongly decreasing the thermal capacity and the thermal conductivity (except at high FEF content ≥80 phr). The influence of the filler on the thermoelastic behaviour of the same composites was also investigated. It was found that the thermoelastic temperature change (ΔT) increased with carbon black concentration as well as the entropy change per unit extension. 相似文献
3.
Xingshuo Zhang Ruotao Feng Junhao Wang Wenqi Wang Jing Hua Zhaobo Wang 《大分子材料与工程》2021,306(6):2000745
Highly efficient oil-water separation shows urgent demand in industrial applications, especially in oil-spill accidents and organic solvent separation. Herein, a novel method is proposed for continuous oil-water separation by a pressure response through valve, which is loaded in a flexible convolute superhydrophobic/superoleophilic film based on low-density polyethylene (LDPE)/ethylene-propylene-diene terpolymer (EPDM) thermoplastic vulcanizate (TPV). The superhydrophobic/superoleophilic LDPE/EPDM TPV film (with contact angles of oil and water are 0° and 161.9°± 2.2°) is prepared only via a molding process where sandpaper is used as the template. The superhydrophobic/superoleophilic property of the TPV film shows robust performance in the activity endurance test. More importantly, the flexible LDPE/EPDM TPV film can be easily rolled up and loaded in through valve, which is the pressure response channel in oil-water separation. The typical separation pressure of oil and water is 3.01 and 6.17 kPa, which means the oil can be completely separated from the oil-water mixture under proper pressure in the pressure response through valve. 相似文献
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Filled covulcanizates of elastomer blend comprising natural rubber (NR) and ethylene‐propylene‐diene rubber (EPDM) of commercial importance were successfully prepared by using a multifunctional rubber additive; namely, bis(diisopropyl)thiophosphoryl disulfide (DIPDIS). A Two‐stage vulcanization technique further improved the physicochemical properties of the blend vulcanizates by restricting, through the formation of polar rubber bound intermediates, the migration of curative and filler from lower to highly unsaturated rubber. Scanning electron microscopy studies indicate homogeneity and coherency in the morphology of the two‐stage vulcanizates. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1001–1010, 2002; DOI 10.1002/app.10361 相似文献
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甲基丙烯酸锌在NBR/木质素中的应用 总被引:5,自引:5,他引:5
研究了α-甲基丙烯酸锌(MAA-Zn)对NBR/木质素(100/100,质量比)硫化胶性能的影响。结果表明,加入1.5~5.0份MAA-Zn,可提高硫化胺的100%的定伸应力,硬度和抗压缩永久变形能力,但对其他力学性能影响甚微,经分析可知,MAA-Zn还可以降低硫化反应活化能,提高硫化胶的交联密度和耐热老化性能。 相似文献
8.
应用AG500A型电子拉力机对硫化橡胶在不同速度、温度下的压缩过程及压缩恒定后的应力变化进行了试验。该结果应用于橡胶油封研制中,取得很好的效果。同时对压缩应力应化对密封效果进行了讨论。 相似文献
9.
用动态剪切模量估算NR与SBR硫化胶的化学交联密度 总被引:2,自引:2,他引:2
用美国Monsanto公司的橡胶加工过程分析仪测定NR和SBR硫化胶或混炼胶料的动态剪切模量(G'),进而根据G_N ̄0=g×2X_0RT和Ge=g'×2X_(ph)RT估算其硫化胶的化学交联密度(X_ch),结果发现:NR/过氧化二异丙苯体系硫化胶和混炼胶料的G'是不同的,但用G'估算的X_ch与用化学分析法测定的结果基本相近;对SBR/促进剂TMTD体系,用这种方法估算的X_(ch)接近用应力-应变法和NMR法的估算值;对NR/促进剂TMTM体系,用G'估算的X_(ch)与用溶胀法获得的数据基本接近。用G'估算X_(ch)法,十分简单、方便。 相似文献
10.
橡胶热老化定量和定性评定方法研究的进展 总被引:7,自引:0,他引:7
叙述了近三十年来在橡胶耐热老化性定量和定性评定方法研究方面所取得的进展,包括两种定量评定方法研究路线的比较,着重叙述了外推计算方法的基础、演变、可靠性及缺陷。同时指出了现行定性评定橡胶耐热老化性标准方法的缺陷及其解决的途径。 相似文献