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1.
《International Journal of Hydrogen Energy》2022,47(9):6377-6387
This work is focused on the explosion characteristics of premixed gas containing different volume fractions of hydrogen in a narrow channel (1000 mm × 50 mm × 10 mm) under the circumstance of stoichiometric ratio. The ignition positions were set in the closed end and the middle of the pipeline respectively. The results showed that when the gas was ignited at the pipeline closed end, the propagating flame was tulip structure for different premixed gas. When the hydrogen volume fraction was less than 40%, the flame propagation speed increased significantly with the rise of hydrogen volume fraction, and the overpressure peak also appeared obviously in advance. However, when the volume fraction of hydrogen was more than 40%, the increase of flame propagation speed and the overpressure peak occurrence time varied slightly. Furthermore, when the ignition position was placed in the middle of the pipeline, the flame propagation speed propagating to the opening end was much faster than that propagating to the closing end, and there was no tulip shape when the flame propagates to the opening end. The flame propagating to the closed end appeared tulip shape under the influence of airflow, and high-frequency flame oscillation occurred during the propagation. This work shows that the hydrogen volume fraction and ignition position significantly affected the flame structure, flame front speed, and explosion overpressure. 相似文献
2.
Xiao-juan Li Yi-xiang Xu Xiang Li Zhi-jiang Jin Jin-yuan Qian 《International Journal of Hydrogen Energy》2021,46(7):5537-5547
Ambient condition, especially the wind condition, is an important factor to determine the behavior of hydrogen diffusion during hydrogen release. However, only few studies aim at the quantitative study of the hydrogen diffusion in a wind-exist condition. And very little researches aiming at the variable wind condition have been done. In this paper, the hydrogen diffusion in different wind condition which including the constant wind velocity and the variable wind velocity is investigated numerically. When considering the variable wind velocity, the UDF (user defined function) is compiled. Characteristics of the FGC (flammable gas cloud) and the HMF (hydrogen mass fraction) are analyzed in different wind condition and comparisons are made with the no-wind condition. Results indicate that the constant wind velocity and the variable wind velocity have totally different effect for the determination of hydrogen diffusion. Comparisons between the constant wind velocity and the variable wind velocity indicate that the variable wind velocity may cause a more dangerous situation since there has a larger FGC volume. More importantly, the wind condition has a non-negligible effect when considering the HMF along the radial direction. As the wind velocity increases, the distribution of the HMF along the radial direction is not Gaussian anymore when the distance between the release hole and the observation line exceeds to a critical value. This work can be a supplement of the research on the hydrogen release and diffusion and a valuable reference for the researchers. 相似文献
3.
Poly(l ‐lactic acid) (PLLA) is a biodegradable and biocompatible thermoplastic polyester produced from renewable sources, widely used for biomedical devices, in food packaging and in agriculture. It is a semicrystalline polymer, and as such its properties are strongly affected by the developed semicrystalline morphology. As a function of the crystallization temperature, PLLA can form different crystal modifications, namely α′‐crystals below about 120 °C and α‐crystals at higher temperatures. The α′ modification is therefore of special importance as it may be the preferred polymorph developing at processing‐relevant conditions. It is a metastable modification which typically transforms into the more stable α‐crystals on annealing at elevated temperature. The structure, kinetics of formation and thermodynamics of α′‐ and α‐crystals of PLLA are reviewed in this contribution, together with the effect of α′‐/α‐crystal polymorphism on the properties of PLLA. © 2018 Society of Chemical Industry 相似文献
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通过馏分切割、温和加氢相结合对中低温煤焦油进行精制处理,精制后的原料采用分级热聚制备中间相炭微球。考察了精制处理条件对原料性质、中间相炭微球宏观外貌及微晶结构的影响。采用FTIR、GC-MS、族组成、元素分析对原料进行表征,采用SEM、XRD对中间相炭微球进行表征。结果表明:中低温煤焦油中300~430℃馏分油是制备中间相炭微球的较佳馏分。300~430℃馏分油中正庚烷可溶物(HS)质量分数高达84.76%,吡啶不溶物(PI)质量分数低至0.23%,杂原子含量低,芳烃化合物的环数为2~4环。300~430℃馏分油在TH=350℃、p=8MPa、t=1.5h、剂油比1∶40(质量比)的条件下温和加氢得到的精制原料,经420℃热聚6h得制备的中间相炭微球宏观外貌、微晶结构较好。中低温煤焦油基炭微球的粒径范围为5~15μm,小球表面光滑,微观结构为地球仪型,经1450℃高温煅烧后,石墨化度达到12.33%。 相似文献
6.
目的:探索炎性疾病患者的乳酸林格氏液(Ringer's lactate,RL)液体动力学特征以及炎性生物标记物是否可以作为协变量影响RL分布和排泄。方法:本研究为前瞻性队列研究。选择40例美国麻醉医师分级(ASA)I-II级,腹腔镜下择期胆囊切除术(胆囊炎组,n=20)或者腹腔镜下急诊阑尾切除术(阑尾炎组,n=20)。所有患者麻醉诱导前开始输注RL,按15 mL/kg,35 min内输毕。采用酶联免疫(enzyme-linked immunosorbent assay,ELISA)方法测定血浆炎症(TNF-α,IL-10和CRP)或者内皮损伤生物标记物(syndecan-1,SDC-1);利用血红蛋白(Hb)稀释-时间曲线和尿量,使用Phoenix软件,采用非线性混合效应模型分析计算RL液体动力学参数和协变量的影响。结果:与胆囊炎组相比,阑尾炎组RL从组织间隙到血浆的转运速率常数(k21)显著降低(14×10-3min-1 versus 35×10-3min-1;P=0.012)。阑尾炎组C反应蛋白(CRP)升高[中位数38.1(1.8-143.6) μg/mL versus 1.3(0.1-159.0) μg/mL;P<0.001];与清醒状态相比,麻醉期间(输液开始后30~45 min),液体从中央室中到外周室的转运速率常数(k12)显著增加(57×10-3min-1 versus 32×10-3min-1;P<0.01)。清除速率常数(k10)降低90%(0.6×10-3min-1 versus 5.3×10-3min-1;P<0.001)。无论在清醒状态还是麻醉状态下低血压均能降低液体清除;炎症或者内膜损伤的生物标记物不能作为显著影响RL液体动力学参数的协变量。结论:阑尾炎或者胆囊炎患者术前输入液体后“炎症反应的生物标记物”不是RL的液体动力学的协变量,但是两组患者中,全身麻醉期间输入液体的清除率下降。 相似文献
7.
Lu Zhang Junjie Shang Tim Pelton Leslee Francis Pelton 《Journal of Computer Assisted Learning》2020,36(4):540-548
With the advent of mobile technologies, well-designed fraction apps can be used to help children gain fraction knowledge, a challenging topic for both teachers and students. The present pilot study adopted a quasi-experimental design to investigate whether children can learn fraction concepts equally well if half of the lesson time (20 min) is replaced with game-based learning. Keeping the total lesson time (40 min) identical, the control group (N = 33) received traditional instruction, and the experimental group (N = 32) was presented with a blended learning approach spending half of the class time (20 min) playing tablet-based fraction games, where each of the learners had their own tablet. The results suggested that in the posttest, the experimental group achieved similar learning gains to the control group and appear to have achieved better performance in the transfer test than the control group. This paper also discusses the efficiency of game-based learning, the mechanism of how fraction games might enhance learning, and the potential of integrating game-based learning in educational settings. 相似文献
8.
《低温学》2015
The development of a high cooling power and high efficiency 4.2 K two stage G-M cryocooler is critically important given its broad applications in low temperature superconductors, MRI, infrared detector and cryogenic electronics. A high efficiency 1.5 W/4.2 K pneumatic-drive G-M cryocooler has recently been designed and developed by ARS. The effect of expansion volume rate and operation conditions on the cooling performance has been experimentally investigated. A typical cooling performance of 1.5 W/4.2 K has been achieved, and the minimum temperature of the second stage is 2.46 K. The steady input power of the compressor at 60 Hz is 6.8 kW, while the operation speed of the rotary valve is 30 rpm. A maximum cooling power of 1.75 W/4.2 K has been obtained in test runs. 相似文献
9.
In different computer models, shape is represented using different methodologies, to varying degrees of precision. This paper examines two approaches to shape representation, and their effects on accuracy in the context of cylindrical particle packing. Two discrete element method (DEM) based software packages are used. A X-ray CT scan of a packed bed provides the experimental measurements for comparison. Eight sphere-composite representations of the same cylindrical pellet were tested. Two of these gave results that quantitatively follow experimental measurements. A range of factors that in theory could affect accuracy of the simulation results are examined, including edge roundedness, surface roughness and restitutional behaviour as a function of sphere-composite representations. The conclusion is that, for packing at least, matching the object's overall shape and dimensions is not enough. Only when a high enough resolution is applied to corners and edges, could the sphere-composite approach possibly match the experimental data quantitatively. 相似文献
10.
针对某厂铜电解种板工序存在的始极片质量波动较大的问题,从种板系统体积控制和添加剂匹配的角度出发,分析各种因素对始极片质量的影响,做出了相应的改进措施,使种板系统运行更加稳定,始极片质量得到进一步提升。 相似文献