多孔硅发光机制的分析

从量子力学的基本理论出发讨论了量子限制效应，推导出多孔硅有效禁带宽度增量并用量子限制效应和表面态及其物质在发光中作用的理论解释了ＰＳ光致发光的实验现象。     

Comparative Study of Models on Confinement of Concrete Cylinders with Fiber-Reinforced Polymer Composites

The use of fiber-reinforced polymer (FRP) composites for strengthening and/or rehabilitation of concrete structures is gaining increasing popularity in the civil engineering community. One of the most attractive applications of FRP materials is their use as confining devices for concrete columns, which may result in remarkable increases of strength and ductility as indicated by numerous published experimental results. Despite a large research effort, a proper analytical tool to predict the behavior of FRP-confined concrete has not yet been established. Most of the available models are empirical in nature and have been calibrated against their own sets of experimental data. On the other hand, the experimental results available in the literature encompass a wide range of values of the significant variables. The objective of this work is a systematic assessment of the performance of the existing models on confinement of concrete columns with FRP materials. The study is conducted in the following steps: the experimental data on confinement of concrete cylinders with FRP available in the technical literature are classified according to the values of the significant variables; the existing empirical and analytical models are reviewed, pointing out their distinct features; the whole set of available experimental results is compared with the whole set of analytical models; and strengths and weaknesses of the various models are analyzed. Finally, a new equation is proposed to evaluate the axial strain at peak stress of FRP-confined concrete cylinders.     

多孔硅发光的物理机制——纳米量子限制效应及表面态在发光中的作用

采用阳极氧化腐蚀的方法制备了多孔硅（ＰＳ），这种ＰＳ的微结构为纳米量级的，并具有光致发光特性，这无疑将对全硅光电子学的发展具有很大意义。根据大量实验与理论分析，提出了这种ＰＳ发光的物理机制：纳米量子限制效应和表面态及其物质在发光中的作用，从量子力学的薛定锷方程出发，用沟道势阱的近似模型，推导得到进入量子线的电子和空穴的能量势垒，ＰＳ的有效带宽Ｅ＝Ｅ＿０＋ΔＥ，对于Ｓｉ（Ｅ＿０＝１．１２ｅｖ）。完美地解释了目前在ＰＳ研究中的ＰＬ谱的篮移现象。     

Smooth Scheduling under Variable Rates or the Analog-Digital Confinement Game

This work considers non-terminating scheduling problems in which a system of multiple resources serves clients having variable needs. The system has m identical resources and n clients; in each time slot each resource may serve at most one client; in each such slot t each client γ has a rate, a real number ρ _γ (t), that specifies his needs in this slot. The rates satisfy the restriction ∑ _γ ρ _γ (t)≤m for any slot t. Except of this restriction, the rates can vary in arbitrary fashion. (This contrasts most prior works in this area in which the rates of the clients are constant.) The schedule is required to be smooth as follows: a schedule is Δ -smooth if for all time intervals I the absolute difference between the amount of service received by each client γ to his nominal needs of ∑ _t∈I ρ _γ (t) is less than Δ. Our objective are online schedulers that produce Δ-smooth schedules where Δ is a small constant which is independent of m and n. Our paper constructs such schedulers; these are the first online Δ-smooth schedulers, with a constant Δ, for clients with arbitrarily variable rates in a single or multiple resource system. Furthermore, the paper also considers a non-concurrent environment in which there is an additional restriction that each client is served at most once in each time slot; it presents the first online smooth schedulers for variable rates under this restriction. The above non-concurrent restriction is crucial in some applications (e.g., CPU scheduling). It has been pointed out that this restriction “adds a surprising amount of difficulty” to the scheduling problem. However, this observation was never formalized and, of course, was never proved. Our paper formalizes and proves some aspects of this observation. Another contribution of this paper is the introduction of a complete information, two player game called the analog-digital confinement game. In such a game pebbles are located on the real line; the two players, the analog player and the digital player, take alternating turns and each one, in his turn, moves some of the pebbles; the digital player moves the pebbles backwards by discrete distances while the analog player moves the pebbles forward by analog distances; the aim of the analog player is to cause one pebble (or more) to escape a pre-defined real interval while the aim of the digital player is to confine the pebbles into the interval. We demonstrate that this game is a convenient framework to study the general question of how to approximate an analog process by a digital one. All the above scheduling results are established via this game. In this derivation, the pebbles represent the clients, the analog player generates the needs of the clients and the digital player generates the schedule. Dedicated to the memory of Professor Shimon Even for his inspiration and encouragement     

The mechanical behaviour of coal with respect to CO2 sequestration in deep coal seams

Carbon dioxide displays a strong affinity for coal due to its propensity to adsorb to the coal surface. The process of CO₂ adsorption on coal causes lowering of surface energy and, it is hypothesised that an associated decrease in surface film confinement results in a decrease in material tensile resistance. Following the results of work carried out on the mechanical influence of CO₂ on brown coal under in situ conditions [Viete DR, Ranjith PG. The effect of CO₂ on the geomechanical and permeability behaviour of brown coal: implications for coal seam CO₂ sequestration. Int J Coal Geol 2006;66(3):204–16], a theoretical explanation is proposed for the perceived lack of a weakening effect with the adsorption of CO₂ to coal at significant confining pressures. We propose that at significant hydrostatic stresses, resistance to failure is otherwise provided (by external confinement) and the effects of adsorptive weakening are concealed. Our model predicts that adsorptive weakening, fracturing under in situ stresses, and associated permeability increases are not an issue for coal seam CO₂ sequestration for sufficiently deep target seams. Lowering of the elastic modulus of coal upon introduction of CO₂ may proceed by means other than surface energy lowering and could well occur irrespective of the depth of sequestration. The effect of elastic modulus lowering under in situ conditions would be beneficial for the long-term retention of sequestered gases.     

A combined dislocation—cohesive zone model for fracture in a confined ductile layer

The collective dislocation behavior near a crack tip in a ductile layer sandwiched between two brittle solids is analyzed via two-dimensional dislocation dynamics (DD) simulations that incorporate a cohesive zone (CZ) model. The cohesive crack tip is treated as part of a much larger finite crack confined in the ductile layer. The underlying boundary value problem is formulated with a set of boundary integral equations and numerically evaluated with a collocation method. The fracture energy of the layered composite material is shown to be strongly correlated with the layer thickness and is directly influenced by the cohesive strength of the ductile layer (Hsia KJ et al. (1994) J Mech Phys Solids 6 877–896).     

Effect of fiber orientation on the structural behavior of FRP wrapped concrete cylinders

In this study, 27 concrete cylinders with a diameter of 152.4 and a height of 304.8 mm were prepared. Among them, 18 cylinders were wrapped using two layers of fiber reinforced polymer (FRP) with six fiber orientations; six cylinders were wrapped using four layers of FRP with fibers in axial or hoop direction only; the remaining three cylinders were used as control. The FRP used was E-glass fiber reinforced ultraviolet (UV) curing vinyl ester. Fifteen coupon specimens were prepared to experimentally determine the tensile strength of the FRP with fibers oriented at 0°, 45°, and 90° from the loading direction. Co-axial compression tests were conducted on the wrapped cylinders and control cylinders. The test results were compared with existing confinement models. It is found that the strength, ductility, and failure mode of FRP wrapped concrete cylinders depend on the fiber orientation and wall thickness. Fibers oriented at a certain angle in between the hoop direction and axial direction may result in strength lower than fibers along hoop or axial direction. A larger database is desired in order to refine the existing design-oriented confinement models.     

Experimental Investigation of Nonconventional Confinement for Concrete Using FRP

The present study investigates experimentally the behavior of concrete confined with fiber reinforced polymers (FRP) in the form of jackets which are applied according to a number of nonconventional techniques. First, the effectiveness of various jacketing configurations combined with anchors as a measure of increasing the strength and deformability of L-shaped columns is investigated. It is concluded that easy to install and low-cost anchors made of resin impregnated fibers properly placed at the reentrant corner of L-shaped columns enable excellent mobilization of confining stresses supplied by the FRP jackets. Next, a number of alternative confinement methods are investigated on concrete cylinders, aimed at quantifying the effectiveness of (1) unbonded jacketing, (2) spirally applied strips attached only at their ends, and (3) jacketing directly on concrete with mortar plastering. Although the study may be regarded as preliminary, it provides useful experimental support to a number of techniques which have the potential to open new horizons in the field of externally applied FRP for enhancing concrete confinement.     

Geotextile filtration opening size under tension and confinement

Nonwoven geotextiles have been used as filters in geotechnical and geoenvironmental works for half a century. They are easy to install and can be specified to meet the requirements for proper filter performance. There are situations where a geotextile filter may be subjected to tensile loads, which may alter relevant filter properties, such as its filtration opening size. Examples of such situations are silty fence applications, geotextile separators, geotextile tubes and geotextiles under embankments on soft soils. This paper investigates the effects of tensile strains on geotextile pore dimensions. A special equipment and testing technique allowed tests to be carried out on geotextile specimens subjected to tension and confinement. The results obtained showed that the variation in filtration opening size depends on the type of strain state the geotextile is subjected, under which the geotextile pore diameter may remain rather constant or increase significantly. However, confinement reduces the geotextile filtration opening size independent on the strain mobilised. An upper bound for the filtration opening size of strained nonwoven geotextiles is introduced and was satisfactory for the geotextile products tested.