稀土元素对钢材性能的影响

针对钢材在高温高压下性能降低等问题,提出在钢材中加入Y、Ce、Zr等稀土元素,通过拉伸实验、高温氧化实验等方法对实验钢进行处理,利用SEM等表征手段观测样品氧化试样的表面形貌,截面形貌及显微组织等情况,最终得出,稀土元素Y、Ce、Zr可以改变钢体组织结构,细化晶粒,增强硬度,提高拉伸强度及屈服强度。     

钛基Ce掺杂SnO_2-RuO_2电极的制备及其对焦化废水的电解处理

采用溶胶-凝胶法制备了经稀土元素Ce掺杂改性的Ti/RuO_2-SnO_2-Ce电极,利用SEM、XRD、EDS等分析方法对电极表面的形貌、物相和涂层成分进行了表征,利用CV曲线、LSV曲线等检测手段对电极的电化学性能进行了测试。以Ti/RuO_2-SnO_2-Ce电极为阳极,钛板为阴极,构建电化学氧化反应装置,并采用其对焦化废水进行电解处理。结果表明,Ti/RuO_2-SnO_2电极经稀土Ce改性后极板表面活性位点数量明显增大,金属涂层的结晶化程度明显增强,电极的催化氧化活性显著提高。室温条件下,保持pH值为7.83,在电流密度为30mA/cm~2,电解时间为30min时,焦化废水经电解处理后COD去除率可达91.63%,TOC去除率可达66.22%,UV254值下降到0.921。     

High Temperature Oxidation Behavior of La2O3-MosSi3/MoSi2 Composites

The oxidation behavior of 0. 8% La2O3- Mo5Si3/MoSi2 composites at 1200℃ in air was investigated. The results reveal that the oxidation resistance of the material with 0. 8% La2O3 and Mo5Si3 is impaired. The oxidation resistance is decreased with increasing Mo5Si3 content. The mass loss follows a linear law in the initial oxidation. With oxidation time prolonging, a continuous and dense oxidation scale prevents oxygen from diffusing increasing when and leads to mass change a Mo5Si3 content is less than 30%. However, the composite shows ＂PEST＂ with the addition of 40% Mo5Si3. With increasing Mo5Si3 content, the oxidation resistance of 0.8% La2O3- Mo5Si3/MoSi2 decreases. This attributes to the poor oxidation resistance of M05Si3 and the relative density decreasing of 0. 8% La2O3-Mo5Si3/MoSi2 composite.     

稀土元素在陶瓷中的应用

从稀土元素的原子结构和化学特性出发,介绍了稀土元素的应用领域,阐述了稀土元素在陶瓷色釉料、各种氧化物陶瓷和非氧化物陶瓷中的应用.     

鄂尔多斯盆地西部环县地区三叠系延长组物源分析

鄂尔多斯盆地西缘三叠系物源认识对油气石油勘探具有重要指导作用。本文通过大量的野外、井下采样，室内分析化验对比研究，发现西部环县地区与六盘山盆地、河西走廊地区延长组有着相似的重矿物组合，砂岩骨架组分普遍有较高的石英含量，稀土、微量元素特征也较为相似，具有属同一沉积体系的特征，花岗岩类是环县三角洲沉积体系的主要物源之一。认为现今概念的鄂尔多斯盆地西部晚三叠世与六盘山盆地及走廊地区不具明显的分割性，盆地很可能向西开口延伸。     

Spin Dependent Hopping in Ti Doped La0.67 Ca0.33 MnO3

A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system.     

Study on Preparation and Electrical Properties of Ba1.03 Ce0.8 Euo.2 O3-a Solid Electrolyte

Ba1.03 Ceo.8Euo.2O3-a solid electrolyte with nonstoichiometric composition was prepared by high temperature sol-id-state reaction. Phase composition, surface and fracture morphologies of the specimen were characterized by using XRD and SEM, respectively. Ionic conduction was researched by gas concentration cell, the performance of hydrogen-air fuel cell was measured in the temperature range of 600-1000℃, and compared them with those of BaCeo.8Euo.203-a and Bao.98Ceo.8Euo.2O3-a. The results indicate that Bat.03Ceo.8Euo.2O3-a is a single-phase perovskite-type orthorhombic system. It is a pure proton conductor in the temperature range of 600-1000℃ in hydrogen atmosphere, and its proton con-duction is superior to that of BaCeo.8 Euo.203-a and Bao.98Ceo.8Euo.203-a, It is a mixed conductor of oxide ion and electron hole in oxygen atmosphere. At 1000℃, the performance of the fuel cell in whieh Ba1.03Ceo.sEuo.2O3-a as electrolyteis higher than that of BaCeo.8Euo,2O33-a or Bao.98Ceo.sEuo.203-a.