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1.
In some sulphide mineral flotation operations, the process water contains high concentrations of calcium and sulphate ions that exceed the solubility limit of gypsum. It has been speculated that the gypsum supersaturated process water would lead to precipitation of gypsum which could coat on mineral surfaces by either nucleation or coagulation, resulting in reduced flotation recovery and selectivity. In this study, a laboratory prepared gypsum supersaturated solution is used to represent the gypsum supersaturated process water, the effect of gypsum supersaturated solution on the surface properties of silica and sphalerite minerals was investigated using zeta potential distribution measurements, scanning electron microscope (SEM), X-ray photon spectroscopy (XPS), Auger electron spectroscopy (AES), and quartz crystal microbalance with dissipation (QCM-D). Our results show that silica and sphalerite minerals carry identical surface charge (−10 mV of zeta potential) in the gypsum supersaturated solution at pH 10 although they are charged differently in simple electrolyte solution at the same pH. Needle shape gypsum precipitates are found in both silica and sphalerite minerals systems conditioned with gypsum supersaturated solution. The gypsum precipitates do not grow on the minerals surfaces but form in the bulk gypsum supersaturated solution. The heterocoagulation between the examined minerals and gypsum particles is insignificant in the gypsum supersaturated solution. It is the high calcium concentration in the gypsum supersaturated solution that has significant effect on the surface properties of silica and sphalerite minerals. The zeta potentials of silica and sphalerite in a 800 ppm calcium solution (similar to the calcium concentration in the gypsum supersaturated solution) are similar to those measured in the gypsum supersaturated solutions. Both silica and sphalerite minerals surfaces are indiscriminately coated with calcium. The surface coating of calcium results in the identical surfaces between silica and sphalerite minerals, and ultimately causes problems for the flotation separation of silica and sphalerite. 相似文献
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由软锰矿,闪锌矿,铁屑直接制取锰锌铁氧体软磁材料新工艺研究 总被引:28,自引:2,他引:26
本文结合磁性材料工艺和锰矿技术特点,创造性地提出由软锰矿、闪锌矿制备锰锌铁氧体材料,克服了锰矿、闪锌矿处理过程的Mn-Zn、Mn-Fe、Zn-Fe分离难题,大大降低了磁性材料生产成本,由于磁性材料产品附加值高,从而为我国丰富的贫锰矿利用找到了一条有效的途径 相似文献
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Although heap leaching is by now well established in the mining industry, the process remains limited by low recoveries with different rate-limiting factors that are not clearly understood. In this study, three large particle size classes (+19/−25, +9.5/−16, +4.75/−5 mm) were prepared from a sphalerite ore by two different methods of comminution (HPGR and cone crusher). The particles were then packed into leach reactors that were operated continuously for 11 months with well-mixed internal circulation of the leach solution. Characterization of the residue of the leach reactors indicated that there are areas within the ore particles where although sphalerite grains are accessible to the solution, they remain unreacted. X-ray tomography and QEMSCAN® analysis of the selected samples before, during and after leaching, showed increased leaching of sphalerite grains associated with pyrite due to galvanic interactions. Mineral chemistry (Fe, Mn content of sphalerite) and jarosite precipitation were also investigated as factors influencing sphalerite leaching. 相似文献
6.
会泽铅锌矿方铅矿、闪锌矿和黄铁矿的浮游性研究 总被引:1,自引:0,他引:1
本文考查了ZnSO4和可溶性淀粉对方铅矿、闪锌矿和黄铁矿浮游性的影响,为会泽铅锌矿铅硫异步等可浮工艺提供了理论依据。试验结果表明,在乙黄药浮选体系中,ZnSO4和可溶性淀粉强烈抑制闪锌矿,而对方铅矿和黄铁矿的浮游性影响不大,且两者的浮游性相近。 相似文献
7.
Mohammad Soleimani Jochen PetersenReza Roostaazad Soheil HosseiniS. Mohammad Mousavi Alireza Najafi Akhtarolmolouk Kazemi Vasiri 《Minerals Engineering》2011,24(1):64-69
In this study, the Geocoat™ technology was used for the extraction of zinc from a mineral concentrate obtained from the Kooshk mine (Yazd, Iran) by a culture dominated by the mesophilic bacterium Acidithiobacillusferrooxidans in a packed column bioreactor. A low grade sphalerite ore was used as support for the concentrate coating. During the 100 days of leaching pH, Fe3+, Fetotal, microbial population density and zinc extraction were measured. The final zinc extraction from concentrate and low grade support was 97% and 78%, respectively, and it was found that leaching from the support does not proceed significantly before leaching from the coating is completed. 相似文献
8.
The flotation response of a typical zinc-lead (Zn/Pb) ore, with respect to coarse composite (sulphide/non-sulphide) particles is reported. The flotation tests were carried out on a selected feed particle size range (−600 + 75 μm, at P80 of 390 μm) and the recovery of Zn composite particles analysed on a size by size basis. The best results were achieved with the use of 75 g/t sodium isopropyl xanthate (SIPX), obtaining a Zn recovery of 77%, with a significant improvement at the coarse end of the particle size distribution. Computerised scanning electron microscope (QEMSCAN) was used to characterise value mineral grain size and degree of liberation, as well as gangue and sphalerite association in particles reporting to both concentrate and tailings. A new characterisation function (Locking ratio, LR) was developed based on the data from the automated mineralogical analysis to characterise particles into two-phase composites with different degree of locking texture (simple and complex). The function, which is based on the mode of occurrence of sphalerite, grain size, proportion and composition of the constituent minerals in each particle, was used to study the flotation response of the particles with different degrees of locking. The results highlight the difference in recoverability of the sphalerite bearing particles with different degrees of locking, with simple locking texture giving higher recovery than complex locking texture, for the same overall liberation. 相似文献
9.
蒙古某高铁、高硫铁闪锌矿石中金属矿物主要有磁铁矿、闪锌矿、黄铁矿等,闪锌矿呈不规则粒状分布,与黄铁矿、磁铁矿等嵌布关系密切,现场采用1粗3精2扫、精选1尾矿返回至磨矿的中矿顺序返回流程选锌,生产指标偏低。为改善选锌指标,进行了选锌药剂用量及闭路流程优化前后选锌效果对比试验。结果表明,在相同药剂制度情况下,模拟现场闭路流程可取得锌品位为50.98%、回收率为91.10%的锌精矿;将现场扫选1精矿也返回磨矿的优化流程可取得锌品位为52.02%、回收率为92.39%的锌精矿,工艺流程的优化使锌精矿锌品位和锌回收率分别提高了1.04和1.29个百分点。 相似文献
10.
广西某铅锌矿属铅低锌高、微细粒嵌布的难分离铅锌矿,铅品位为0.88%、锌品位为9.19%。主要含锌矿物为闪锌矿,含铅矿物较复杂,主要为脆硫锑铅矿、硫锑铅矿和方铅矿,且嵌布粒度极微细。为了高效开发利用该矿石资源,对该矿石进行了铅、锌分离回收试验研究。结果表明:在磨矿细度为-0.074 mm占80%的情况下,采用1粗2扫3 精选铅,1粗2扫3 精选锌,铅、锌1次精选尾矿和1次扫选精矿合并返回再磨,其余中矿顺序返回流程处理该矿石,最终获得了锌品位为48.05%、锌回收率为91.13%的锌精矿,以及铅品位为26.63%、锑品位为21.80%、铅回收率为87.46%、锑回收率为86.30%的铅锑精矿,铅锑精矿铅含量较低的原因与矿石中主要含铅矿物脆硫锑铅矿和硫锑铅矿理论含铅量较低、嵌布粒度极微细有关,不适合细磨深选。 相似文献