High-resolution FIB-TEM-STEM structural characterization of grain boundaries in the high dielectric constant perovskite CaCu3Ti4O12

In this work, the grain boundaries composition of the polycrystalline CaCu₃Ti₄O₁₂ (CCTO) was investigated. A Focused Ion Beam (FIB)/lift-out technique was used to prepare site-specific thin samples of the grain boundaries interface of CCTO ceramics. Scanning transmission electron microscopy (STEM) coupled with energy dispersive X-ray spectrometry (EDXS) and Electron Energy Loss Spectroscopy (EELS) systems were used to characterize the composition and nanostructure of the grain and grain boundaries region. It is known that during conventional sintering, discontinuous grain growth occurs and a Cu-rich phase appears at grain boundaries. This Cu-rich phase may affect the final dielectric properties of CCTO but its structure and chemical composition remained unknown. For the first time, this high-resolution FIB-TEM-STEM study of CCTO interfacial region highlights the composition of the phases segregated at grain boundaries namely CuO, Cu₂O and the metastable phase Cu₃TiO_4.     

Effect of focused ion beam sample preparation on the phase composition of zirconia

The investigation of phase transformations in metastable ceramic systems such as zirconia often requires local phase analysis within the areas of interest. Electron backscatter diffraction is a suitable method in combination with focused ion beam sample preparation. The interaction between ion beam and sample has to be carefully considered. In case of metastable Y-PSZ and Mg-PSZ, phase transformations were observed after FIB preparation with 30?kV, 30?nA and 5° incidence angle. Damage was the dominating effect for angles of 72°. The expected local temperature increase due to the ion bombardment with 30?kV and 30?nA is 700?K for ZrO₂. Thus, the observed phase transformations can be explained on the basis of the temperature increase in the corresponding Y-PSZ phase diagram. In case of Mg-PSZ, the transition temperature is 1083?°C. The local temperature increase was obviously lower. The excitation energy for the observed phase transformation was smaller than expected from the phase diagrams of the thermodynamic equilibrium. Using 5?kV, 4.8?nA and 5° incidence angle, no phase transformations and no damage were observed. Thus, these conditions are well suited for the FIB preparation of metastable zirconia.     

微球聚焦测井仪小极板的理论及实验研究

本文对微球聚焦测井仪小极板进行研究，利用有限元法计算了小极板的均质及非均质Ｋ值，并与实验结果进行了比较，结果表明理论值怀实验值吻合较好，说明了理论计算的正确性，给出了对应于小极板的泥饼校正图版及屏流比曲线，对小极板的推广应用有实用价值。     

低渗透率地层渗透率的确定方法

结合大庆油田外围低渗透率地层的地质特点,根椐渗流理论和岩心分析资料,分析了地层渗透率与孔隙度、组成地层的各种矿物含量以及泥质含量之间的关系,建立了不同矿物组合地层的渗透率计算方程。用本方法计算的和岩心分析的渗透率进行了对比,二者之间具有较好的一致性。     

中子寿命测井在评价管外窜槽中的应用

管外窜槽已成为制约中原油田注水开发的障碍，并造成了严重的经济损失。文中分析了管外窜槽的形成机理，重点介绍了注硼中子寿命测井技术用于管外窜槽监测的原理、工艺及解释方法。结合中原油田的应用实例，论证了中子寿命测井评价管外窜槽的有效性，为油藏动态监测提供了有效手段。     

关于碳氧比测井的几个问题

本文根据碳氧比测井技术的发展现状,提出5个值得讨论的问题,并较详细地阐述了对这些问题的看法。这5个问题是:碳氧比测井的地质—物理基础、总门本底谱、数字与模拟量传输技术、对仪器幅度稳定性的要求和仪器屏蔽系统设计。     

X441对数放大器的原理及其应用

本文主要介绍X441单片对数放大器的基本原理和应用,并列举了一些具体应用电路。     

测量生产井含水率的一种新方法：—屏蔽式感应法

提出了利用屏蔽式感应线圈测量生产井中油水混合物的混合电导率进而推断含水率的方案,并用几何因子理论对仪器设计参数范围进行了估算。结果表明,使用1～5MHz的工作频率,二次场感应信号可达到μV数量级。从原理上看,该方案能测量高含水率的油水混合物,并且不受金属套管的影响。     

SUN工作站生产测井解释系统（PLASYS）

吕永军,胡亚兵,毕卓新.SUN 工作站生产测井解释系统(PLASYS).测井技术,1993;17(2):114～120Sun 工作站生产测井解释系统,是以 SUN GKS 为基本软环境支持,在 SUN 工作站上开发完成的一套生产测井资料解释与处理系统。本文详细叙述了该系统的构成、解释原理、输入输出等,并通过实例说明了该系统的解释结果。     

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岩心分析过程中的取心间隔并非完全相同，这就形成了非等间距的岩心分析数据。测井曲线的数据一般都是采样等间距的，为了使岩心数据与测井数据更好地进行匹配，对岩心分析数据进行插值处理，使分析数据形成等距的形式，然后对插值后的数据根据不同的测井曲线进行滤波，使得岩心分析数据与测井数据的分辨率相匹配，利用处理后的数据建立模型或数据分析才可得到较为准确的模型。克里金插值和分形插值均为非线性的数学插值方法，它们与一般的数学插值方法相比较，能更好地反映数据的内在分布规律。文中分别利用克里金插值和分形插值的理论对岩心数据的插值进行了深入的研究，根据两种插值方法的理论建立了相应的插值方法。经过对两种插值理论的实例对比分析，得到了两种非线性插值方法的优缺点，为进一步的深入研究奠定了一定基础。