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《Ceramics International》2020,46(14):22282-22289
Self-assembly is an emerging strategy for preparing composite cathodes with good oxygen electrochemical reduction activity and congenital chemical compatibility for intermediate-temperature solid oxide fuel cell (IT-SOFC). Here we report that a self-assembled BaCo0.6Zr0.4O3-δ (BZC-BC) nanocomposite is prepared through one-pot glycine-nitrate process and exhibits high cathode performance. The BZC-BC nanocomposite is composed of 62 mol% cubic perovskite BaZr0.82Co0.18O3-δ (BZC) as an ionic conductor and 38 mol% hexagonal perovskite BaCo0.96Zr0.04O2.6+δ (12H-BC) as a mixed ionic and electronic conductor. The BZC-BC nanocomposite has the pomegranate-like particles aggregated with a larger number of nanoparticles (50-100 nm) which greatly enlarge the three-phase boundary sites. The BZC-BC nanocomposite exhibits a thermal expansion coefficient of 12.89 × 10−6 K−1 well-matched with that of Ce0.8Gd0.2O3-δ (12.84 × 10−6 K−1) electrolyte. The high electro-catalytic activity of BZC-BC nanocomposite cathode for oxygen reduction is reflected by the low polarization resistances of oxygen ions incorporation at cathode/electrolyte interface (0.02823 Ω cm2), oxygen species diffusion (0.03702 Ω cm2) and oxygen adsorptive dissociation (0.07609 Ω cm2) at 700 °C. The single cell with BZC-BC nanocomposite cathode achieves the maximum power density of 1094 mW cm−2 at 650 °C and shows good stability under 25 h run. 相似文献
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Adaptive robust boundary control of shaft vibrations under perturbations with unknown upper bounds 下载免费PDF全文
This paper presents robust and adaptive boundary control designs to stabilize the two‐dimensional vibration of hybrid shaft model. The hybrid shaft is mathematically represented by a set of partial differential equations, governing the shaft vibrations, coupled to ordinary differential equations, describing rigid body spinning and dynamic boundary conditions. The control objective is to stabilize the transverse vibrations of the perturbed shaft while regulating the spinning rate. To achieve this, the paper first establishes robust boundary control laws that fulfil the control objective in the presence of modeling uncertainties and external disturbances operating over the shaft domain and boundary. Lyapunov‐based analyses show that the proposed robust control exponentially stabilizes the shaft with vanishing distributive perturbations, while assuring ultimately bounded vibrations in the case of nonvanishing perturbations. Then, adaptive control philosophy is utilized to achieve redesigned robust controllers that only use online adaptation of control gains without acquiring the knowledge of bounds on perturbations, as well as dynamic parameters. An advantage of this design is avoiding an overconservative robust control law, which may induce poor stability and chattering in tackling system perturbations with unknown upper bounds. Simulations through finite element method illustrate the results. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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针对柳洪水电站压力管道下斜段洞身长、倾角陡、工期紧、地质条件复杂、安全隐患突出等问题,开挖中采用反井钻开挖斜井导孔与人工开挖斜井导洞对接技术,安全隐患少,施工效率高。介绍了反井钻开挖大倾角斜井导孔的施工程序、操作步骤和导孔纠偏措施。在反井钻施工中通过调整主副泵工作压力、转速,合理调整稳定钻杆分布等措施控制孔斜,取得了反井钻实际钻孔129 m、平均日进尺7.5 m、导孔钻头落在距斜井中轴线下方1.8 m处的良好效果,成功与人工开挖导洞对接。 相似文献
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高速往复式内燃机平衡轴低质量设计分析 总被引:2,自引:0,他引:2
分析了扇形和偏心圆两种平衡轴设计的要求以及平衡重低质量的设计原则。扇形平衡重半径及宽度应尽量大、夹角应尽量小。偏心圆平衡重的偏心圆半径应尽可能大 ,轴承半径应尽可能小。同样质量的扇形平衡重产生的平衡力比偏心圆平衡重要大。 相似文献
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武山铜矿主井延深时根据新的采、选工艺要求,在前期工程的基础上,对其箕斗提升系统进行改造,增设坑内破碎。针对该矿特粘的矿石性质和前期工程遗留问题,在具体设计和实施过程中采取特别措施保证系统通畅和安全并注意节省投资。同时对尚存在的问题也提出了新的思考。 相似文献
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In Malaysia, no long-term daylight data are measured. It was only recently that the need to measure the availability of daylight became urgent when the importance of daylighting in buildings was rediscovered. The hourly daylight availability has been simulated for the Malaysian sky using daylight modelling techniques based on empirical and measured solar irradiation and cloud cover data. This paper presents the techniques involved in producing exterior illuminance data. These data were then compared with measured illuminance at Shah Alam and Bangi, Malaysia. The global illuminance levels are generally high, with values exceeding 80,000 lux at noon during the months when solar irradiation is highest. Even during the months when the ground receives less solar irradiation, the peak illuminance can reach 60,000 lux. Applications and uses of such data are in daylighting design, both for visual and thermal comfort, task illuminance and energy-conscious design of buildings. Recommendations are made at the end of the paper on the various climatic data that are required to be measured for overall daylighting design applications. 相似文献