Decay Rate Kinetics of Ozone Gas in Rice Grains

The present study was carried out to evaluate the effects of ozone on rice grains for the following three conditions: saturation time, decay rate, and half-life of ozone. Experiments were performed in different bed thicknesses (5 and 10 cm) and moisture content (11.4 and 14.2% wb) at atmospheric conditions. The lowest saturation time of ozone was 119 min, with the concentration of 516 ppm for rice grains ozonated at 5-cm bed thickness with 11.4% (wb) moisture content. The decay rate kinetics of ozone obtained were consistent with a first-order model. Regarding the half-life of ozone, the lowest value obtained was 6.78 min for rice grains ozonated at 10-cm bed thickness with 14.2% (wb) moisture content.     

气液固三相相平衡热力学模型与计算方法

原油中含有大量的高分子有机固相物质，因此，要准确地描述油气体系相平衡，必须对气液固三相相平衡进行研究，在对高分子有机烃类沥青沉降机理有了一定的认识的基础上，提出了大的交互作用系数，可以描述沥青与原油中轻质不相容性的程度。根据对油气烃类混合物体系的一般性认识与提出的沥青组分特征化方法，导出了与之相应的有其自身特殊性的气液沥青三相相平衡物料平衡方程组，用考虑沥青沉降三相闪蒸数值算法，对沥青沉降进行有效的理化模拟计算，此外，结合实例分析，给出了沥青质参考逸度的计算，饱和压力和沉降量的拟合方法。     

Separating n-alkane mixtures by exploiting differences in the adsorption capacity within cages of CHA, AFX and ERI zeolites

The saturation capacity of n-alkanes in CHA, AFX and ERI zeolites, that consist of cages separated by windows, decreases with increasing carbon number. The major aim of the present communication is to demonstrate the possibility of separating n-alkane mixtures relying on differences in saturation capacities. To investigate this possibility, Configurational-Bias Monte Carlo simulations for adsorption of C3–nC6, nC4–nC6, and nC5–nC6 mixtures in CHA, AFX and ERI were carried out for equimolar bulk fluid phase. These mixture simulations show that for operation at fluid phase fugacities below about 1 MPa, the adsorbed phase in equilibrium with the bulk vapor phase is predominantly the alkane with the longer chain length, i.e. nC6. However, for operation at pressures in excess of 1 MPa, the adsorbed phase in equilibrium with the bulk liquid phase is richer in the component with the smaller chain length. In some cases, the nC6 is practically excluded from the zeolite.     

Numerical study on PEMFC’s geometrical parameters under different humidifying conditions

Steady-state and three-dimensional simulations were carried out to study the influences of geometrical parameters on the performance of PEMFC under different hydrating conditions. Flow fields, species transport, transport of water in polymer membrane and movement of liquid water in cathode and anode porous layers were determined, in order to accomplish a complete estimation of ohmic and concentration losses of PEMFC power. The geometrical parameters were thickness of the polymer membrane, cathode catalyst layer as well as gas channel to rib width ratio. Every simulation was made under different relative humidities of inlet flows (50 and 100%) for every change of characteristic length. Results show that the influence of the geometrical parameters on ohmic and concentration losses is of considerable importance. The performance of PEMFC is seriously affected under dehydrating conditions. However, such performance may be considerably improved by using suitable geometrical parameters. Cathode and anode liquid saturation may not only affect the transport of species, but also the polymer electrolyte water content. These results show the importance of simultaneously calculating both the water absorption and desorption through the polymer electrolyte and the liquid saturation in the cathode and anode porous mediums to obtain an actual view of ohmic and concentration losses of the PEMFC performance.     

Numerical simulations of cantilever beam response with saturation control and full modal coupling

Numerical simulations of the response of a uniform, cantilever beam subjected to a base excitation are performed. A saturation absorber is implemented to control the beam response. In previous investigations of similar configurations, the inertial and structural properties of the piezoelectric actuators have been neglected, resulting in an analytical model of a uniform beam. This investigation includes the nonuniformities in the beam properties that are introduced when piezoelectric actuators are bonded to the uniform beam. The resulting coupling between uniform, cantilever beam modes is fully included in the analytical model. It is shown that this modal coupling has a significant effect on the beam response, which is not present when modal coupling is neglected.     

On stability of an input amplitude constrained predictive control system

This paper presents stability results for discrete-time model-based predictive control system subject to an input amplitude constraint. It is shown that the input amplitude constrained control system may provide a stable control system in the sense of BIBO when the system to be controlled is of a class of the system poles which consist of multiple integrators and a stable polynomial. The solution of Diophantine equations and their properties are addressed. Simulation study is also carried out and it is shown that the output of the system may converge to the reference signal for certain degree of constraints.     

油水相对渗透率曲线在特高含水油藏中的应用

运用相对渗透率曲线计算了纵向砂体的剩余油饱和度分布,结果表明,当油田综合含水率为98%时,水驱剩余油饱和度为40.13%,可动油饱和度为13.41%,油层存在非均质性,在剩余油饱和度相对高的部位仍有一定潜力;濮南沙二上2 3油藏平均油水相对渗透率曲线具有较好的代表性,可以在特高含水油藏中应用。     

On the Performance of Ozone Generators Working with Dielectric Barrier Discharges

The parameters, which determine the performance of ozone generators, are efficiency and maximum ozone concentration. The efficiency from oxygen has been found to be nearly independent on the kind of barrier discharge arrangement (volume, surface, coplanar), while the ozone concentration saturation level depends on the specific design of the generator. These phenomena are explained with features of the discharge process and the properties of chemical reactions, respectively. The importance of a limit in the energy density of the discharge is highlighted.     

不同湿度混凝土动力抗压性能数值模拟分析

本文基于随机骨料建立了二维混凝土的细观数值模型,利用无厚度cohesive单元模拟界面层及基体的损伤,用弹性单元模拟孔隙水,并结合黏性效应、惯性效应,模拟分析了应变率和孔隙含水率对混凝土抗压强度、峰值应变和弹性模量的影响。结果表明:动力分析时混凝土组成材料采用静力参数,考虑了惯性效应与黏性作用后,数值模型可以很好地反映动力荷载作用下混凝土名义动力强度增长因子(DIF)、单轴压缩弹性模量和峰值应变随应变率增加而增加的宏观现象,以及随着孔隙含水率增加混凝土静动态抗压强度线性减小、DIF线性增加、率效应增强的变化规律。以应变率和孔隙含水率为参数,提出了以干燥混凝土静态抗压强度为基准的含水混凝土动态抗压强度的预测公式。