Structural properties of inorganic materials: tungsten bronze SBN ceramics

Rare-earth doped strontium barium niobates were synthesized using usual ceramic technique. The dopants are La, Ce, Gd, Sm and Nd. The materials were characterized by XRD and density measurements. The grain sizes were determined from SEM analysis. Lattice parameters changed uniformly with rare-earth dopants in unfilled structures. Density measurements and SEM analysis confirmed only minute changes in the densities of the ceramics.     

新型长余辉稀土发光材料发光特性探讨

本文对新型长余辉稀土发光材料在不同照度 ,不同激发时间等多种条件下的发光特性进行了检测 ,并对检测结果进行了分析讨论。     

Structure and Magnetic Properties of LaCo_(13-X)M_X Intermetallic Compounds

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氟碳铈矿／直氟碳钙铈矿混层结构中新规则混层矿物的超微结构研究

用电子衍射和晶格像技术研究了钙稀土氟碳酸盐矿物中的氟碳铈矿（Ｂ）／直氟碳钙铈矿（Ｓ）混层结构，发现并确定了Ｂ＿４Ｓ＿４、Ｂ＿８Ｓ＿６、Ｂ＿１Ｓ＿６、Ｂ＿７Ｓ＿４和Ｂ＿２Ｓ＿１５种新规则混层矿物的对称性、晶胞参数及理论晶体化学式。根据所获得的高分辨晶格像真实而直观地揭示出该类Ｂ＿ｍＳ＿ｎ（ｍ＞ｎ）型新规则混层矿物的长周期有序堆垛结构特征及变化规律。     

Synthesis of nano particle of inorganic oxides by polymer matrix

Ultrafine (⩽ 150 nm) powders of spinels [MFe₂O₄ where M = Ni(II), Co(II) and Zn(II)]; rare-earth orthoferrites [RFeO₃ where R = Sm, Nd and Gd], and rare-earth garnets [R₃Fe₃O₁₂ where R = Sm, Nd and Gd] with good purity and chemical homogeneity were prepared through two new versatile chemical routes. The first route involved the coprecipitation of the desired metal nitrates from their aqueous solution, in presence of a water soluble polymer-polyvinyl alcohol (PVA), by triethyl ammonium carbonate solution. The other process involved complete evaporation of a mixture of optimum amounts of PVA and the desired aqueous metal nitrate solutions, with and without the addition of optimum amounts of urea when the mixture was evaporated to a pasty mass. In addition, detailed study on the reported potassium ferricyanide route was also carried out for the production of the rare-earth orthoferrite powders. The various precursor as well as the heat-treated mixed-oxide powders, prepared through each of the routes, were compared by the physical characterization studies involving thermal gravimetry and differential scanning calorimetry, infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, and room temperature magnetic measurements.     

快速低温固体S—C—N三元共渗工艺研究

以木炭、尿素和硫化铁为渗剂,用稀土化合物CeCl_3作催渗剂,于570℃进行固体S-C-N三元共渗。试验结果表明,在相同时间内加催渗剂的渗层深度比不加催渗剂的有大幅度提高,且硬度及耐磨性亦有较大提高,硬度梯度较平缓。离子探针分析表明,稀土元素Ce亦被渗入钢的表面,它不仅起到活化渗剂的作用,同时在提高钢的性能方面还起到微合金化的作用。     

稀土碳氮共渗及其机理研究

本文研究了稀土元素在气体碳氮共渗中的作用,并系统地提出了稀土催化机理。     

含稀土硅化铁热电材料的电学性能初探

采用悬浮真空熔炼和800℃,168h真空退火方法制备了含稀土Sm的FeSi2基金属硅化物,并对其晶体结构、See-beck系数、电阻率进行了初步研究。实验发现,名义组成为Fe0.6Sm0.4Si2的试样的热电功率因子从室温时的0.26×10-4W·m-1K-2随温度上升到500℃时的1.6×10-4W·m-1K-2,比不含Sm或含Sm量很少的对比试样高一个数量级左右。其原因被认为是由于Sm的外层4f电子的贡献。     

碳纳米管及稀土元素钇(Y)对高Ni含量Ti(C,N)基金属陶瓷组织与性能的影响

研究了不同含量的碳纳米管及0.8%稀土Y对高Ni含量Ti(C,N)基金属陶瓷组织性能的影响.将不同成分的试样分别于1400℃、1410 ℃、1420℃真空烧结,测试抗弯强度、洛氏硬度,观察背散射电子形貌、断口形貌并做能谱分析.结果表明,加入质量分数(下同)为0.8%Y及0.3%～1.0%的碳纳米管时,碳纳米管含量为0.5%的组织较均匀,芯壳结构明显,抗弯强度及硬度均较高.     

用于燃油节能环保的有机稀土活性复合物的制备及应用

由有机稀土配体化合物、表面活性剂、助表面活性剂、稳定剂、溶剂等原料制备出有机稀土活性复合物。通过柴油机台架实验发现,该种复合物的加入不仅对柴油机节能、抗磨损及保护发动机起到积极的作用,同时能有效降低尾气中有害物质的排放。