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排序方式: 共有99条查询结果,搜索用时 93 毫秒
1.
Fatemeh Sadat Razavi Morteza Hajizadeh-Oghaz Omid Amiri Maryam Sadat Morassaei Masoud Salavati-Niasari 《International Journal of Hydrogen Energy》2021,46(1):886-895
The study of the effect of different chelating agents in the Pechini method on the morphology has been a promising strategy that can be used for practical tuning of the nanoparticle's morphology and hence the electrochemical hydrogen storage capacity. In the current study, the conventional Pechini sol-gel approach was used to prepare the Ba2Co9O14 nanoparticles as a novel hydrogen storage material. The X-ray diffraction investigation approved the formation of Ba2Co9O14 with a Hexagonal crystal structure for all of the synthesized samples. The scanning electron microscopy (SEM) revealed when citric acid was used as a chelating agent, nanoparticles with finer and more uniform morphology were obtained rather than other chelating sources. The transmission electron microscopy (TEM) showed in the presence of citric acid; the size of the synthesized nanoparticles was between 14 and 24 nm. According to the Diffuse Reflectance Spectroscopy (DRS) analysis, the calculated bandgap of synthesized nanoparticles was approximately 3.2 eV, which indicates that synthesized nanoparticles were semiconductors in essence. The electrochemical hydrogen adsorption/desorption results showed that the sample synthesized by the citric acid has an enhancement in electrochemical hydrogen storage of approximately 800 mAh/g after 15 cycles. 相似文献
2.
Mary C.F. Alves Severino J.G. Lima José W.M. Espinosa Luiz E.B. Soledade Iêda M.G. Santos 《Materials Letters》2009,63(1):118-120
Strontium stannate (SrSnO3), a perovskite material, was synthesized by the polymeric precursor method, with different routes to eliminate organic matter. The utilization of pure oxygen for the elimination of organic matter changed the Raman spectra, especially in the low frequency region. Some peaks, which were previously assigned to the perovskite phase, were not noticed when the carbonate amount was lower. On the other hand, the profile of the IR spectra and XRD patterns did not change. These results suggest that carbonate may be present inside the perovskite lattice. 相似文献
3.
Effect of Ni on Pt/C and PtSn/C prepared by the Pechini method 总被引:1,自引:0,他引:1
T.S. AlmeidaK.B. Kokoh A.R. De Andrade 《International Journal of Hydrogen Energy》2011,36(6):3803-3810
Different compositions of Pt, PtNi, PtSn, and PtSnNi electrocatalysts supported on carbon Vulcan XC-72 were prepared through thermal decomposition of polymeric precursors. The nanoparticles were characterized by morphological and structural analyses (XRD, TEM, and EDX). XRD results revealed a face-centered cubic structure for platinum, and there was evidence that Ni and Sn atoms are incorporated into the Pt structure. The electrochemical investigation was carried out in slightly acidic medium (H2SO4 0.05 mol L−1), in the absence and in the presence of ethanol. Addition of Ni to Pt/C and PtSn/C catalysts significantly shifted the onset of ethanol and CO oxidations toward lower potentials, thus enhancing the catalytic activity, especially in the case of the ternary PtSnNi/C composition. Electrolysis of ethanol solutions at 0.4 V vs. RHE allowed for determination of acetaldehyde and acetic acid as the reaction products, as detected by HPLC analysis. Due to the high concentration of ethanol employed in the electrolysis experiments (1.0 mol L−1), no formation of CO2 was observed. 相似文献
4.
R. Chaiyont C. Badoe C. Ponce de León J. L. Nava F. J. Recio I. Sirés P. Herrasti F. C. Walsh 《化学工程与技术》2013,36(1):123-129
A film of iridium and tin dioxides doped with antimony oxide (IrO2‐SnO2‐Sb2O5) was deposited onto Ti mesh and plate substrates by the Pechini method. The electrode surface morphology and composition were characterized by SEM‐EDS. The ternary oxide coating was used for the anodic oxidation of methyl orange (MO) azo dye. Linear sweep voltammetry was used to identify the electrode potentials that favour MO degradation. Batch electrolyses were then carried out at a constant electrode potential of 1.5, 1.75 and 2.0 V vs. SHE using either a three‐electrode batch cell or a flow reactor. The dye solutions were totally decolorized via reactive oxygen species, such as ?OH, H2O2 and O3 formed in situ from water oxidation at the Ti/IrO2‐SnO2‐Sb2O5 surface. 相似文献
5.
Various trivalent oxides were added as co-dopants to gadolinia-doped ceria (GDC) electrolyte used for solid oxide fuel cells at up to 5 mol%. An examination was made on how they affect the electrical conductivity of the electrolyte and, eventually, the open-circuit voltage (OCV) of a unit cell. Through a comparison of the thermal expansion coefficients (TEC), it was investigated whether or not the co-doped electrolytes are thermomechanically compatible with other cell components. The addition of co-dopants generally improve the electrical properties of the electrolyte by yielding greater OCV values and not changing the TEC significantly (5% at most), except in the case of Pr. Among the electrolytes examined, the one co-doped with Sm (3 mol%) shows the best improvement in performance. 相似文献
6.
采用胶溶法、缓释反应法和Pechini工艺等三种不同的溶胶 凝胶方法制备YBCO超导材料,观测了合成物的结构以及超导性能等。结果表明:Pechini工艺制备的粉体纯度高,颗粒细小、均匀,经960℃长时间烧结后,可获得高纯度的YBCO超导材料,超导临界转变温度Tc=92K,跃迁宽度ΔT<1K。 相似文献
7.
8.
用Pechini工艺制备了PdO 纳米粉末.对粉末进行了 DTA、TG 等热分析,利用 XRD 微结构数据对粉末的成分及其长大行为进行了分析研究 .研究结果表明,当热处理温度低于500 ℃时 ,PdO粉末粒径增长迅速 ,而热处理温度高于 500 ℃时 ,粉末生长缓慢.运用相变理论计算了两个阶段的晶粒长大激活能,表明低温区粒子生长激活能比高温区(500 ℃以上) 高出几倍. 相似文献
9.
Min Hyuk Kim Ming Zi Hong Young-Suk Kim Hyunsuk Lee Keon Kim 《Electrochimica acta》2006,51(27):6145-6151
The dissolution of nickel oxide cathode in the electrolyte is one of the major technical obstacles to the commercialization of molten carbonate fuel cell (MCFC). To improve the MCFC cathode stability, the alternative cathode material for MCFC was prepared, which was made of Co/Ce-coated on the surface of Ni powder using a polymeric precursor based on the Pechini method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDAX) were employed in characterization of the alternative cathode materials. The Co/Ce-coated Ni cathode prepared by the tape-casting technique. The solubility of the Co/Ce-coated Ni cathode was about 80% lower when compare to that of pure Ni cathode under CO2:O2 (66.7:33.3%) atmosphere at 650 °C. Consequently, the fine Co/Ce-coated Ni powder could be confirmed as a new alternative cathode material for MCFC. 相似文献
10.
Lithium niobate thin films have been deposited on Pt/Ti/SiO2/Si(100) substrates by Pechini method. Characterization of the initial precursor solutions containing citric acid (CA), niobium and lithium ions has been performed by Fourier transform infrared spectroscopy, Raman spectroscopy and carbon nuclear magnetic resonance spectroscopy. The results indicate that citric acid coordinate to niobium ions to form a niobium-CA complex through one terminal carboxyl group, the hydroxyl group and the central carboxyl group as a tridentate ligand. The thermal decomposition of the Li-Nb precursors gel powder has been studied and the results show that LiNbO3 phase is formed directly from the thermal decomposition of the precursor gel. By heat-treatment at 600 °C for 2 h, polycrystalline LiNbO3 thin films with smooth and crack-free surface could be achieved. 相似文献