Formation and thermal stability of amorphous Ni-Mo-P alloys

The experimental researches on the chemical deposition of Ni-Mo-P amorphous alloys were carried out by adding Na2 MoO4 into acidic solutions. The optimum technology conditions were obtained by orthogonal design experiments. The structures and the relationship between compositions and their thermal stability were studied by energy spectrum (EC), scanning electron micrograph and X-ray diffraction spectrum. Compared with Ni-P amorphous alloys, the Ni-Mo-P amorphous alloys have high crystallization temperature and thermal stability, and the hardness reaches its peak when the annealing temperature is 500 ℃. With the increase of the heat treatment temperature, the surface morphology of the alloys changes.     

电流卡钳传输阻抗的线性补偿

为了扩展电流卡钳的频率测试范围,根据其等效电路模型,分析并测试了传输阻抗特性,发现了传输阻抗在频率范围内的非线性现象,进而提出了基于放大器的线性补偿方法.通过测试结果表明,在1-50kHz的被测信号情况下,匹配了放大器的电流探头的传输阻抗的波动范围≤±1dB.因而,利用这一补偿方法,可以给单片机信号采集转换成被测电流值带来方便.     

Development and test in grid of 630 kVA three-phase high temperature superconducting transformer

Abstract A 630-kVA 10.5 kV/0.4 kV three-phase high temperature superconducting (HTS) power transformer was successfully developed and tested in a live grid. The windings were wound by hermetic stainless steel-reinforced multi-filamentary Bi2223/Ag tapes. The structures of primary windings are solenoid with insulation and cooling path among layers, and those of secondary windings consist of double-pancakes connected in parallel. Toroidal cryostat is made from electrical insulating glass fiber reinforced plastics (GFRP) materials with room temperature bore for commercial amorphous alloy core with five limbs. Windings are laid in the toroidal cryostat so that the amorphous core operates at room temperature. An insulation technology of double-half wrapping up the Bi2223/Ag tape with Kapton film is used by a winding machine developed by the authors. Fundamental characteristics of the transformer are obtained by standard short-circuit and no-load tests, and it is shown that the transformer meets operating requirements in a live grid. __________ Translated from Proceedings of the CSEE, 2007, 27(27): 24–31 [译自:中国电机工程学报]     

非晶合金变压器的节能效果及应用

介绍了非晶合金变压器的性能特点及目前应用情况,结合汉中农村配电网实际情况,计算分析比较了非品合金变压器和S9变压器的综合节能效益,为非晶合金变压器在西部农村配电网中的应用提供科学依据。     

Analysis of the infrared transmission data of hydrogenated amorphous silicon film fabricated by high rate PECVD

The optical properties of hydrogenated amorphous silicon thin films prepared by a new thermocatalytic plasma enhanced chemical vapor deposition (PECVD) method are here reported for the first time. The transmission spectrum of the film, deposited at a rate of 1.5 nm/s, was measured between 500 and 1100 nm. The envelopes of the transmission spectrum interference maxima and minima were analyzed to reveal the absorption coefficient α(λ@#@), the refractive indexn(λ), the average thickness of the film (791 nm) and the variation of the thickness (11.4 nm), using an analysis which takes into account film inhomogeneity. The modified Newton's method of numerical analysis was used to obtain the optical parameters. The optical band gap ε₀} was determined to be 1.69 eV from the absorption coefficient spectrum, commensurate with values quoted for lower deposition rate PECVD films. The value for ε₀}, the small variation of the film thickness, and a value for the defect density of 3.7 x 10¹⁵}cm^-3} determined for similar material in other work indicate that the thermocatalytic PECVD method can produce acceptable quality films at a high deposition rate.     

Influence of sputtering conditions on the solar and luminous optical properties of amorphous LixWoy thin films

Thin films of amorphous tungsten oxide were deposited by sputtering onto glass substrates coated by conductive indium–tin oxide. The films were sputtered at different oxygen-to-argon flow ratios with different pressure and power. Elastic recoil detection analysis determined the density and the stoichiometry. X-ray diffraction measurements showed that the films were amorphous. The films were electrochemically intercalated with lithium ions. At several intercalation levels of each film, the optical reflectance and transmittance were measured in the wavelength range 0.3–2.5 μm. We study the effect of various sputtering conditions on the coloration efficiency of the films and on the luminous and solar optical properties. The O₂/Ar ratio and the sputter pressure determine to a large extent the optical absorption. As-deposited sputtered tungsten oxide with sufficiently little oxygen exhibits an absorption peak similar to the case of lithium intercalation.     

板状Fe-基大块非晶合金的制备及其断裂韧性测定

采用电弧熔炼母合金、普通铜模吸铸工艺 ,制备出尺寸规格为 2 0mm× 10mm× 1mm的板状Fe -Co -Zr -Mo -W -B系Fe -基大块非晶合金。经DTA检测 ,所制备的Fe -基非晶合金具有明显的玻璃转变温度和较宽的过冷液相区 (Tg=884K ,ΔTx≥ 6 0K)。采用压痕试验法测定了该板状Fe -基大块非晶合金的断裂韧性 ,其铸态断裂韧性在 1.6MPa·m1/ 2 量级。     

Characterization of amorphous Ni-Si binary alloy films by flash evaporation

We previously reported on an extremely small temperature coefficient of resistivity (TCR) of thin amorphous Ni-Si film resistors fabricated by new flash evaporating method, which have a wide range of resistivity.¹ In the present paper, we describe the structural and chemical properties of these films for the purpose of clarifying the cause of resistive change of films resulting from heat treatment. X-ray diffraction patterns show that Ni-Si films with greater than 20 wt.% Si remains predominantly amorphous after heat treatment. Changes in composition and binding energy of the films resulting from heat treatment are measured by means of XPS. Electrical characteristics are also investigated as a function of Si concentration and temperature. The resistance variations resulting from heat treatment are found to originate from a structural change. The activation energy needed for this change is obtained by analyzing the extent of change during isothermal heating and found to vary from 1 eV to 2.5 eV with increasing Si content from 20 wt.% to 80 wt.%.     

ZL111铝合金表面Ni-Cr-Al激光熔覆层中的非晶组织

利用５ｋＷＣＯ２激光器激光熔覆铝合金表面的Ｎｉ－Ｃｒ－Ａｌ涂层,ＳＥＭ与ＴＥＭ分析结果表明,在激光熔覆层中存在有非晶组织,非晶组织呈空间扭曲薄片或杉叶状,它们分别存在于熔覆层颗粒间白色网状组织与颗粒中