Spin probe study of semi‐interpenetrating polymer networks based on polyurethane and polymethacrylate functional prepolymers

The motional transition and heterogeneity of semi‐interpenetrating networks (SIPNs) based on polyurethane (PU) with carboxylic groups and methacrylic copolymer (PM) with tertiary amine groups were studied by the electron spin resonance (ESR) spin probe method. The concentration of functional groups in both prepolymers varied from 0 to 0.45 mmol g^?1. Spin‐probed SIPNs show that the temperature‐dependent spectra are sensitive to polymer interactions imposed by functional groups. These interactions determine the free volume distribution in the matrix and temperature at which motional transition takes place. The fraction of free volume increases with functional group concentration and reaches its maximum at 0.25 mmol g^?1. Further increases in the functional group concentration reduce the free volume. The results of the networks with strong interactions are discussed in terms of the interference of the plasticizing effect of the PU component and the formation of possible cluster cross‐links, which restricts segmental motions. Copyright © 2003 Society of Chemical Industry     

露天矿半连续工艺技术应用现状及发展前景

介绍了露天矿半连续工艺技术国内外应用现状、研究成果以及发展趋势。     

唐钢薄板坯连铸连轧生产中半无头轧制技术分析

介绍了热轧薄带钢生产中半无头轧制的优点，并对唐钢薄板坯连铸连轧生产中半无头轧制的工艺方案和关键技术进行了技术分析。     

Effect of Rare Earth Elements on Thermal Fatigue Property of Low Chromium Semi-Steel

The effect of rare earth elements on eutectic carbide‘s morphology of low chromium semi-steel in as-cast state and after heat treatment was investigated, and accordingly, the thermal fatigue property of this material was studied. The results show that RE can improve the eutectic carbide‘s morphology, inhibit the formation and propagation of thermal fatigue cracks, therefore, promote the thermal fatigue property, which is more noticeable in case of the RE modification in combination with heat treatment. The optimal thermal fatigue property can be obtained when treated with 0.2% RE modification as well as normalization at 950℃ for 3h.     

Semi‐Global Output Feedback Stabilization for a Class of Uncertain Nonlinear Systems

This paper addresses the problem of semi‐global stabilization by output feedback for a class of nonlinear systems whose output gains are unknown. For each subsystem, we first design a state compensator and use the compensator states to construct a control law to stabilize the nominal linear system without the perturbing nonlinearities. Then, combining the output feedback domination approach with block‐backstepping scheme, a series of homogeneous output feedback controllers are constructed recursively for each subsystem and the closed‐loop system is rendered semi‐globally asymptotically stable.     

Feedback predictive control for constrained fuzzy systems with Markovian jumps

In this paper, a feedback model predictive control method is presented to tackle control problems with constrained multivariables for uncertain discrete‐time nonlinear Markovian jump systems. An uncertain Markovian jump fuzzy system (MJFS) is obtained by employing the Takagi‐Sugeno (T‐S) fuzzy model to represent a discrete‐time nonlinear system with norm bounded uncertainties and Markovain jump parameters. To achieve more generality, the transition probabilities of the Markov chain are assumed to be partly unknown and partly accessible. The predictive formulation adopts an on‐line optimization paradigm that utilizes the closed‐loop state feedback controller and is solved using the standard semi‐definite programming (SDP). To reduce the on‐line computational burden, a mode independent control move is calculated at every sampling time based on a stochastic fuzzy Lyapunov function (FLF) and a parallel distributed compensation (PDC) scheme. The robust mean square stability, performance minimization and constraint satisfaction properties are guaranteed under the control move for all admissible uncertainties. A numerical example is given to show the efficiency of the developed approach. Copyright © 2011 John Wiley and Sons Asia Pte Ltd and Chinese Automatic Control Society     

半固态灰铸铁的制备与显微组织

建立了一种不需搅拌和其它附加处理的半固态灰铸铁制备技术 ,用浇注前合理调整熔体温度或调温 适当快冷的铸造方法 ,并配以合适的凝固冷却速度 ,成功地制备了球状初生奥氏体圆整、尺寸细小、分布均匀的半固态亚共晶灰铸铁 ,得到了最佳工艺条件 ,并用铸铁金相计算机辅助检测系统 ,对初生奥氏体的形状系数和等效直径进行了测量与统计分析 ,定量描述了半固态组织的特性     

A Semi‐Batch Process for Nitroxide Mediated Radical Polymerization

Summary: A semi‐batch process using nitroxide mediated polymerization, was explored for the design of low molecular weight solvent‐borne coatings, typical of those used in the automotive industry. While living radical polymerization (LRP) offers many advantages in the control of polymer chain microstructure that may confer important physical and chemical property benefits to coatings, adapting LRP to a semi‐batch process poses significant challenges in the design and operation of the process. Using styrene monomer, various two‐component initiating systems (free radical initiator, 4‐hydroxy‐TEMPO) were studied to understand the effects of different initiators on the course of polymerization. In addition, an alkoxyamine was synthesized and used as the initiating source. The initiators Luperox 7M75 and Luperox 231 give higher polymerization rates and reasonable control over polymerization, while benzoyl peroxide (BPO), Vazo 67, and the alkoxyamine are less effective. The number of polymer chains in the final product is always less than the theoretical value, reflecting poor initiation efficiency, probably resulting from undesirable termination reactions that become important due to the nature of the semi‐batch process. Adding camphorsulfonic acid (CSA) or charging initiator concurrently with monomer during semi‐batch feed, can increase the polymerization rate while maintaining the living character of the polymerization. The copolymerization of styrene and butyl acrylate is also shown to exhibit living character.

Schematic representation of the exchange reaction to produce N‐TEMPO capped polymer chains.     

基于磁流变阻尼器的车辆悬架系统模糊半主动控制

在对磁流变液和磁流变阻尼器的研究基础上 ,以磁流变阻尼器作为半主动控制元件组成模糊半主动悬架系统。运用数值仿真和试验研究等方法对基于磁流变阻尼器的模糊半主动悬架进行了研究。数值仿真和试验结果表明 ,设计的模糊半主动控制算法可对基于磁流变阻尼器的半主动控制悬架实现有效的控制     

3000m~3/h排烟循环流化床脱硫工艺中试实验研究

介绍了采用真实烟气的 30 0 0m3 /h排烟循环流化床烟气脱硫工艺 (CFB FGD)及其中间试验装置 ,通过实验研究了钙硫摩尔比 (Ca/S)、近绝热饱和温度差 (ΔT)、烟气湿度、喷水量、入口SO2 浓度、浆液雾化质量、脱硫灰循环等对脱硫效果的影响。实验表明 ,CFB FGD工艺在停留时间小于 6s、烟气流速v =4— 6m/s、Ca/S =1.2、ΔT =10— 12℃时可实现高达 90 %的脱硫效率。