Effect of functionalized silicon carbide nano-particles as additive in cross-linked PVA based composites for vibration damping application

In this research study, a comprehensive effort has been made to functionalize silicon carbide particles using the acidic oxidation with nitric acid to obtain homogeneous stabilized distribution of activated SiC particles within a polymer matrix, and develop functionalized silicon carbide (f-SiC) particle reinforced polyvinyl alcohol (PVA) based cross-linked composite. After fabrication of functionalized silicon carbide (f-SiC) particle reinforced polyvinyl alcohol based cross-linked composite with varying f-SiC weight percentages of PVA (0%, 1%, 2%, 3%, and 4%) were placed to various investigations. Processed samples are initially examined based by the physical tests (water absorption tests), followed by mechanical test (tensile test) and then micro-structural tests (scanning electron microscopy). Lastly, thermal tests were also concluded which involved the dynamic mechanical, differential thermal and thermo gravimetric analysis. The cross-linked polyvinyl alcohol-based composite with 2 weight % of f-SiC content is observed to be the superlative of all the compositions under this research study that was confirmed by the mechanical and micro-structural tests. This composite material shows high storage modulus with visco-elastic behavior, therefore, the material can be utilized to diminish the transmission of noise, as a shock absorber and vibration isolator.     

Microstructured extremely thin absorber solar cells

In this paper we present the realization of extremely thin absorber (ETA) solar cells employing conductive glass substrates functionalized with TiO₂ microstructures produced by embossing. Nanocrystalline or compact TiO₂ films on Indium doped tin oxide (ITO) glass substrates were embossed by pressing a silicon stamp containing a μm size raised grid structure into the TiO₂ by use of a hydraulic press (1 ton/50 cm²). The performance of these microstructured substrates in a ETA cell sensitized by a thermally evaporated or chemical bath deposited PbS film and completed by a PEDOT:PSS hole conductor layer and a Au counter electrode is compared to that of planar substrates. Surprisingly planar films produced better performance than micro-structured films. A simple model implying photoconductive shunting paths revealed by junction breakdown at negative bias under illumination is presented.     

复杂微结构三维形貌测量方法的研究

微结构三维形貌测量是研究微加工工艺和微尺寸特性的重要测试内容。本文提出一种基于相移显微干涉术、利用干涉陶建立二维结构模板指导相位展开的新方法，它不仅适用于静态测量，而且能应用于在动态测量中，特别是微机电系统（MEMS）器件的运动测量。以微谐振器为测试器件，对其运动梳齿结构进行了静态三维形貌测量，实验的离面理论测量精度优于0．5nm，测试结构内部的面内理论测量精度优于0．5μm，而边缘尺寸因受到边缘提取方法的影响，其测量精度仅在μm量级。对该方法的缺点和发展方向做了探讨。     

Bending-stretching analysis of thick functionally graded micro-plates using higher-order shear and normal deformable plate theory

In the present article, higher-order shear and normal deformable plate theory together with modified couple stress theory are developed to study the bending analysis of thick functionally graded rectangular micro-plates. One material length scale parameter is used for capturing the size effects. Utilizing the variational approach and also a principle of virtual displacement, a new form of equilibrium equations and the corresponding boundary conditions are derived. It is assumed that material properties vary through the thickness according to the power law function. Finally, an analytical solution for the bending problem of a simply supported FG rectangular micro-plate is presented.     

蝶翅结构负载银颗粒表面增强拉曼散射性能

将银粗糙化的蝶翅三维结构引入到表面增强拉曼散射(surface enhanced Raman scattering, SERS)基材中,提高检测效果。采用绿带翠凤蝶蝶翅作为基板,将纳米银金属颗粒负载其上,合成了经有序粗糙化的表面增强拉曼散射基底。采用场发射扫描电镜及透射电镜分析了有序银粗糙化蝶翅SERS基底的形貌特征。并以罗丹明6G作为探针分子,可检测到浓度低至10^-14mol/L的标样溶液,且检测效果好于二维平板SERS基底,经计算得到绿带翠凤蝶SERS基底的增强因子为1.57×10⁷。在试验的基础上,结合三维有限时域差分的计算方法(finite difference time domain, FDTD),模拟计算得到绿带翠凤蝶SERS基底的电场强度E分布,其log|E|²的值为3.85,其对激发光的反射率仅为6%。研究表明银粗糙化的蝶翅三维结构,可以使表面的电场强度有显著增强。     

波长和气氛对激光诱导硅表面微结构的影响

为了研究特定气氛下激光辐照对单晶硅表面微结构的影响,采用红外(基频波长1064nm)和紫外(3次谐波波长355nm)YAG纳秒激光脉冲连续辐照方法,分别在SF6、空气、N2和真空环境下对硅表面微结构进行了实验研究。得到红外纳秒激光在SF6和空气中形成的微结构较真空和N2下有更高的纵横比;紫外纳秒激光在SF6和真空中产生的锥形结构比N2和空气中要更为显著,但SF6中形成的微结构上有絮状物的结果。结果表明,激光波长和环境气氛对微结构的形成起着决定性作用,且激光辅助化学刻蚀的效率不同。该结果对深入研究纳秒激光在特定气氛下诱导硅表面微结构是有帮助的。     

基于白光干涉无重叠拼接的微结构表征方法

针对白光干涉技术(WLI)应用于大范围测量时图像重叠拼接会引入误差并降低测量效率这一缺欠,本文基于纳米测量机(NMM)提出了一种无重叠拼接的白光干涉测试方法。利用NMM的高精度定位能力,扩展了普通白光干涉仪的测量范围,实现了对微结构近4倍于CCD视场的大范围测量,验证了无重叠图像拼接的可实现性。     

松辽西斜坡地区构造特征及其控油作用

依据地震和钻/测井资料,结合前人研究成果,在松辽西斜坡地区展开了嫩江组-青白口组地层的构造特征研究。结果表明:西斜坡地区主要经历了坳陷期和反转期构造运动,断裂类型多样,主体呈北北东和北北西向延伸,整体规模较小。平面上,区域构造自西向东可分3个带：西部简单斜坡带,中部背斜带和东部洼陷带。研究区微幅度构造发育,中部背斜带易形成断背斜型、断鼻型和构造-岩性型圈闭。以高角度、小断距为特征的断裂多形成垂向输导通道,广泛发育的背斜-岩性类构造输导脊构成了良好的油气运移路径,沟通了东部洼陷带的烃源岩,控制着油气的聚集成藏。     

橡胶基体极性对高填充量橡胶/黏土纳米复合材料微观结构与性能的影响

研究了橡胶基体极性对高填充量橡胶/黏土纳米复合材料（RCNs）微观结构及性能的影响,探讨了硫化过程对极性环境不同的RCNs微观结构及性能的影响机理。研究表明：橡胶基体的极性对RCNs近程微观结构和远程微观结构都会产生一定的影响。RCNs中黏土片层会因高压作用（硫化过程）而发生远程聚集,但近程微观结构会因橡胶基体极性的不同而发生不同的变化;有机黏土的加入可以对RCNs的力学性能、气体阻隔性能有显著的改善。RCNs的力学性能与其远程微观结构关系密切;RCNs的气体阻隔性能则因黏土含量的不同而受到近程微观结构和远程微观结构的共同影响;远程微观结构较好的RCNs（如NBRCNs）的气体阻隔性能会在较低的黏土用量下进入增长平台阶段,黏土高用量情况下,相对气体透过率主要取决于近程微观结构。     

镁合金AZ31高温形变机制的织构分析

利用X射线衍射和背散射电子衍射方法测定了镁合金AZ3l高温动态再结晶和超塑形变时的宏观和微观织构,分析了晶粒内部的形变机制.结果表明,在动态再结晶和超塑形变过程中,晶粒内部的滑移机制仍起重要作用,表现为再结晶晶粒出现择优取向以及一些晶粒可充分均匀形变成长条状.宏观织构的测定表明,具有不同初始织构的两类样品高温动态再结晶时,新晶粒有不同的取向择优过程,形成相似的织构;长条形变晶粒内部开动的滑移系也有一定的差异.分析了不同温度下相同的织构对应的不同塑变机理取向成像分析表明,基面织构取向的晶粒间总伴随着较高比例的小角晶界和30°(0001)的取向关系,这是六方结构的六次对称性限制了动态再结晶时(亚)晶粒间取向差的有效增大的缘故.