Evidence of fluid evolution of Baoshan Cu−Pb−Zn polymetallic deposit: Constraints from in-situ sulfur isotope and trace element compositions of pyrite

In-situ LA-ICP-MS and S isotopes of pyrite from the Baoshan Cu polymetallic deposit were conducted to investigate the ore-forming process and the enrichment mechanism of elements. Three generations of pyrite (Py I, Py II, and Py III) in the skarn-type ores and pyrite in the carbonate-hosted sulfide ores from central, western, and northern (C_Py, W_Py, and N_Py) mining districts are selected for comparison. Compared with Py I and Py III, the contents of most elements in Py II are apparently higher. The As and Se contents are high within a wide range and are decoupled in the growth band of the C_Py. The highest As, Se, and Pb contents were found in W_Py and N_Py. These results indicate the drastic changes in the temperature and fluid mixing during the mineralization. The occurrence of fluctuation and change in temperature and f(O₂) was triggered by intermittent pulses of magmatic-hydrothermal fluids, mixing with meteoric water, and water−rock interactions. The sulfur isotopes of all species of pyrite indicated the magmatic source. The change in the f(O₂) conditions caused slight differences in the sulfur isotope compositions. Consequently, a metallogenic model was proposed to explain the ore-forming processes.     

铁碳填料对电镀清洗废水的微电解性能

以硫铁矿烧渣为主要材料制备了球形铁碳填料,并将其用于电镀清洗废水的处理。由交互正交试验结果可知,废水pH值是影响COD和氨氮去除率的主要因素,其次是废水pH值与铁碳填料添加量的交互作用和废水pH值与反应时间的交互作用。微电解的最佳工艺条件为:废水pH值2.50,铁碳填料的添加量15 g/L,反应时间30 min。此时,COD降低78.6%,氨氮降低15.0%,处理效果比商品铁碳填料的好。     

河南某硫酸烧渣制备氯化铁铵的试验研究

以河南某硫酸烧渣为原料, 采用盐酸浸出-浓缩净化-氯化铵诱导-冷却结晶工艺制备优级纯氯化铁铵晶体。实验所得最佳工艺条件为: 盐酸溶液浓度40%、液固比8∶1、浸出温度85 ℃、浸出时间40 min、氯化铵过量系数0.9, 此条件下原料中铁浸出率为91.43%, 所制备的氯化铁铵纯度达到99.85%。     

某高硫矽卡岩型金铜矿选矿试验研究

针对高硫矽卡岩金铜矿中黄铁矿含量高、难抑制特点,采用对黄铁矿捕收能力非常弱的Z-200和丁基铵黑药作为浮选捕收剂,在低碱度条件下(pH值9.5)实现了铜与金的综合回收。研究结果表明:闭路试验混合精矿铜品位为21.15%、金品位为24.11g/t,铜和金的回收率分别可达93.92%和83.73%,选矿指标较为理想。     

Effect of Biochar as Reductant on Magnetizing-roasting Behavior of Pyrite Cinder

The effect of biochar substituted for anthracite as reductant on magnetizing-roasting pyrite cinder was investigated.The key of magnetizing-roasting is the gasification reaction between reductants and CO2.Since biochar could react with CO2 more rapidly at lower temperature,the reactivity of biochar is better than that of anthracite.The gasification of biochar could produce reducing condition ofφCO/(φCO+φCO2)about 10%-20% between 700-800 ℃,which is in accord with the atmosphere and temperature of Fe2O3 reduction.So it is beneficial to the reduction of iron mineral of pyrite cinder.Compared with anthracite,biochar could decrease the roasting temperature from825 to 750 ℃ and roasting time from 20 to 15min,which shows that a better effect of magnetization could be obtained in the condition of lower temperature and shorter time.Using biochar as reductant,iron concentrate extracted from pyrite cinder as about 64%iron grade could be produced,and the recovery is over 90% under the condition of above 90% grinding particle less than 0.045 mm and magnetic intensity of 0.124-0.194 T.     

湖南沃溪金锑钨矿床中成矿物质来源的硫同位素地球化学证据

沃溪AuSbW矿床是湖南湘西前寒武纪地层中最具有代表性的金矿床之一,位于扬子准地台江南地轴南缘的雪峰弧形构造隆起带的中段。矿石以石英-金-硫化物型为主,与金共存的矿石矿物为辉锑矿、黑钨矿、白钨矿、黄铁矿等。文章对沃溪矿床深部矿段中辉锑矿和黄铁矿的硫同位素地球化学进行了研究,结果表明:黄铁矿的δ~(34)S变化范围-4. 05‰～0.42‰,极差4. 47‰,平均值-1. 54‰;辉锑矿的δ~(34)S变化范围-4. 99‰～-1. 52‰,极差3. 47‰,平均值-2. 87‰。δ~(34)S变化范围小,说明其来源的均一性,同时与赋矿的马底驿组富硫围岩的δ~(34)S很相近,表明硫来源于赋矿地层。同时,δ~(34)S具有从浅部向深部增大的趋势。     

胶东乳山金矿金青顶矿区黄铁矿热电性研究

金青顶金矿黄铁矿α值离散性较大。Ｐ型黄铁矿出现率为８１．３％。导型组合在早成矿期Ⅰ－ｌ→Ⅰ－４阶段的变化是：Ｐ＞Ｎ→Ｐ》Ｎ→Ｐ》Ｎ→Ｐ＞Ｎ；在晚成矿期Ⅱ－２→Ⅱ－３阶段的变化为Ｐ＜Ｎ→Ｐ》Ｎ。在矿化地段，由上而下，αｐ减小，αＮ增大；Ｐ％减小，Ｎ％增大。其影响因素主要为黄铁矿中Ｃｏ，Ｎｉ，Ａｓ，Ｓｂ，Ｔｅ的含量，其次为结晶温度。用黄铁矿导型和αｐ均值所作矿物学填图反映的结果基本一致，从中可以取得有关黄铁矿形成温度，矿床剥蚀程度，矿体特征，深部远景和控矿构造等标型信息。     

调浆气氛对黄铁矿浮选电化学性质影响研究

基于氧气在黄铁矿浮选电化学反应中的作用,考察了p H为4.00、6.86、9.18、10.01和10.96五种缓冲溶液浮选体系下,矿浆溶氧量(DO)对黄铁矿浮选矿浆电位(Eh)和回收率的影响。研究表明,五种缓冲溶液体系下,Eh均随着DO的增加而增加,碱性条件下DO对Eh的影响较小;浮选回收率随DO的增加呈下降趋势,碱性条件下回收率的变化较大。     

紫金山铜金矿黄铁矿碎裂结构特征及其地质意义

紫金山铜金矿黄铁矿的碎裂结构具有三种赋存状态,主要运用电子探针(EPMA)对其进行微区分析,进而探讨碎裂结构黄铁矿的特征及其地质意义。通过研究得出以下主要结论:1)本矿碎裂结构黄铁矿的三种赋存状态:破碎程度一般,颗粒较大;破碎程度大,颗粒细小;碎裂结构与粒状结构黄铁矿共生。黄铁矿的破碎程度越大,颗粒越细小,含金性越大,且黄铁矿中金的赋存状态为纳米级颗粒金;2)碎裂结构黄铁矿是亏铁富硫型的,从浅部到深部,亏铁程度与富硫程度逐渐减弱,黄铁矿的Co-Ni图解,说明其是火山—热液成因,其形成与早期隐爆作用有关;3)碎裂结构黄铁矿的主要微量元素有Cu、Co、Ni、Pb、Zn、Au、Ag、As、Sb、Se、W、Sn等,从浅部到深部,碎裂结构黄铁矿的微量元素Sn含量明显增加;元素W、Au、Zn、Ag、Pb都有逐渐降低的趋势;Ni含量也逐渐降低,但是靠近铜矿体,其含量有所增加;越接近铜矿体,Cu与S的含量增加,而Fe的含量降低,体现了紫金山铜金矿床的成矿流体是火山热液(形成于燕山晚期,富含Cu、Au、Pb、Zn等成矿元素)与紫金山复式花岗岩岩体(形成于燕山早期,具有W、Sn、Mo、Bi等矿化特征)的叠加。