全文获取类型
收费全文 | 1272篇 |
免费 | 79篇 |
国内免费 | 39篇 |
专业分类
电工技术 | 25篇 |
综合类 | 49篇 |
化学工业 | 482篇 |
金属工艺 | 77篇 |
机械仪表 | 15篇 |
建筑科学 | 35篇 |
矿业工程 | 34篇 |
能源动力 | 51篇 |
轻工业 | 19篇 |
水利工程 | 64篇 |
石油天然气 | 23篇 |
武器工业 | 2篇 |
无线电 | 91篇 |
一般工业技术 | 170篇 |
冶金工业 | 221篇 |
原子能技术 | 13篇 |
自动化技术 | 19篇 |
出版年
2024年 | 3篇 |
2023年 | 31篇 |
2022年 | 41篇 |
2021年 | 47篇 |
2020年 | 48篇 |
2019年 | 33篇 |
2018年 | 57篇 |
2017年 | 55篇 |
2016年 | 50篇 |
2015年 | 43篇 |
2014年 | 51篇 |
2013年 | 59篇 |
2012年 | 83篇 |
2011年 | 91篇 |
2010年 | 59篇 |
2009年 | 79篇 |
2008年 | 58篇 |
2007年 | 74篇 |
2006年 | 68篇 |
2005年 | 53篇 |
2004年 | 39篇 |
2003年 | 51篇 |
2002年 | 31篇 |
2001年 | 40篇 |
2000年 | 26篇 |
1999年 | 30篇 |
1998年 | 16篇 |
1997年 | 9篇 |
1996年 | 11篇 |
1995年 | 11篇 |
1994年 | 3篇 |
1993年 | 13篇 |
1992年 | 6篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有1390条查询结果,搜索用时 0 毫秒
1.
通过对MgO:LiNbO3参量过程温度相位匹配及走离角,允许参量等运转参数的理论计算与分析,确定了晶体的切割角度θ=82℃,以近非临界相位匹配(NCPM)取代NCPM,将温度调节范围控制在较低的温度上,研制了532nm泵浦的MgO:LiNbO3温度调谐脉冲光学参数振荡器(OPO),在800~1700nm波段实现连续调谐输出。参量泵浦功率密度阈值为57.3MW/cm^2,泵浦能量约2倍阈值处,单谐振(SRO)参量转换效率为11%以上。 相似文献
2.
采用激光感生荧光技术测量了Nd:MgO:LiNbO3晶体的偏振荧光光谱,简要地说明了Nd:MgO:LiNbO3双晶体腔内互倍频的基本原理,并在实验中用染料激光作泵浦源实现了其双晶体腔内互倍频运转;得到543nm横模倍频绿光单端输出约YMW,腔前泵浦阈值约38MW,总转换效率约为1.3%。 相似文献
3.
The partial oxidation of methane over the supported Rh (0.8 wt.%) catalysts was investigated. Two kinds of supports were used, MgO and Ti-modified MgO (prepared by grafting technique). Among the Ti-modified MgO supports, two different compounds were used as source of Ti: inorganic (chloride) and organic (alkoxide). The catalytic performance of Rh-supported catalysts depends on the support and varies in the sequence: Ti-MgO/I > Ti-MgO/O > MgO. Ti-containing catalysts exhibited higher activity and selectivity compared to MgO, which is especially noticeable at low temperature. Possible explanations for the phenomena observed were proposed on the basis of characterization results. 相似文献
4.
Zhihong Xu Tao Jiang Hao Zhang Yujun Zhao Xinbin Ma Shengping Wang 《Frontiers of Chemical Science and Engineering》2021,15(3):698
Novel MgO-doped CaO sorbent pellets were prepared by gel-casting and wet impregnation. The effect of Na+ and MgO on the structure and CO2 adsorption performance of CaO sorbent pellets was elucidated. MgO-doped CaO sorbent pellets with the diameter range of 0.5-1.5 mm exhibited an excellent capacity for CO2 adsorption and adsorption rate due to the homogeneous dispersion of MgO in the sorbent pellets and its effects on the physical structure of sorbents. The results show that MgO can effectively inhibit the sintering of CaO and retain the adsorption capacity of sorbents during multiple adsorption-desorption cycles. The presence of mesopores and macropores resulted in appreciable change of volume from CaO (16.7 cm3∙mol−1) to CaCO3 (36.9 cm3∙mol−1) over repeated operation cycles. Ca2Mg1 sorbent pellets exhibited favorable CO2 capture capacity (9.49 mmol∙g−1), average adsorption rate (0.32 mmol∙g−1∙min−1) and conversion rate of CaO (74.83%) after 30 cycles. 相似文献
5.
为了掌握高Al2O3条件下(w(Al2O3)为15%以上)高炉渣系的熔化特性,利用差式扫描量热仪分析了不同w(MgO)/w(Al2O3)、碱度(R)以及w(Al2O3)对高铝高炉渣的熔化温度及熔化热的影响。试验结果表明,炉渣熔化开始温度为1 248~1 291 ℃、熔化结束温度为1 432~1 485 ℃、熔化热为137~211 J/g;当w(Al2O3)=15%、高w(MgO)/w(Al2O3)时,发生了共晶逆反应,导致高炉炉渣熔化开始温度逐渐降低,但由于高炉炉渣的液相线温度基本未变,所以炉渣熔化结束温度基本未发生改变;w(Al2O3)为20%时,随着w(MgO)/w(Al2O3)的增加,炉渣中易生成熔点较高的镁铝尖晶石,导致高炉炉渣熔化开始温度逐渐增大,与此同时,炉渣液相线温度逐渐降低,导致炉渣熔化结束温度逐渐降低;随着碱度R的增加,高炉炉渣中生成了具有高熔点的化合物、炉渣的液相线温度升高,使得高炉炉渣的熔化开始温度逐渐增加、炉渣熔化结束温度逐渐升高;随着w(Al2O3)的增加,发生了共晶逆反应,故炉渣的熔化开始温度逐渐降低,而随着w(Al2O3)的增加,炉渣中键能较大的Al—O键增多,需要在更高温度下才能实现炉渣的最终熔化,即熔化结束温度逐渐增加;随着w(MgO)/w(Al2O3)、R以及w(Al2O3)的增加,炉渣熔化热逐渐增多。分析认为,随着R的增加,炉渣中有高熔点化合物的生成,熔化热增加;随着炉渣中w(Al2O3)的增加,炉渣中Al—O键增多,解聚破坏熔渣结构消耗的热量增多;而随着w(MgO)/w(Al2O3)增加,高熔点化合物的生成或熔化开始温度降低,造成熔化热增加。 相似文献
6.
The early stage oxidation and evaporation of Mg-9%Al-1%Zn alloy 总被引:1,自引:0,他引:1
F. Czerwinski 《Corrosion Science》2004,46(2):377-386
Thermogravimetric technique was used to determine the oxidation and evaporation behaviour of AZ91D magnesium alloys with 5 and 10 ppm of beryllium at temperatures between 200 and 500 °C. Depending on temperature and time, the alloy experienced protective or non-protective oxidation with linear or accelerated oxide growth kinetics. During reaction in an oxidizing atmosphere, the additions of beryllium delayed the transient from the protective to non-protective scale formation. In an inert atmosphere, increased beryllium contents reduced the magnesium evaporation rate. 相似文献
7.
Three MgO surfaces of different structures have been employed as models for study of the acid-base properties of MgO. Surface spectroscopies including XPS, UPS, and ISS were used to determine the nature and the absolute coverage of surface intermediates, and the nature of bonding sites upon adsorption of Brønsted acid molecules on these surfaces. Different behavior patterns of the Brønsted acid molecules with varying strengths on the three model surfaces provide insights into the site requirements for dissociation of Brønsted acids on MgO. The base-catalyzed Cannizzaro reaction of formaldehyde was observed on these model surfaces under UHV conditions. 相似文献
8.
Mixed oxide catalyst prepared by co-precipitating magnesium oxide and calcium oxide showed an excellent activity for the oxidative coupling of methane. The high performances were presumed to arise from the high basicity of the mixed oxide. 相似文献
9.
Ping Shen Lifeng Zhang Jianxun Fu Hao Zhou Yi Wang Limei Cheng 《Ceramics International》2019,45(9):11287-11295
In the present study, the wettability between liquid iron with two different Al contents and MgOAl2O3 binary substrates was studied in reducing atmosphere. The contact angles between liquid iron with 18?ppm Al and MgO, MgO·Al2O3, Al2O3 were 133.5°, 113.7°, 126.9° respectively. With the variation of the substrate composition, the contact angles for the intermediate binary phases of the three components (MgO, MgO·Al2O3, Al2O3) obeyed the Cassie theory. In the experiment using iron with 370?ppm Al, all the contact angles were higher than that using low Al-containing iron. The surface of the iron drop was covered with an oxide layer, which mainly consisted of many small particles. With the variation of the substrate gradually from MgO to Al2O3, the composition of the oxide layer changed from MgO·Al2O3 to CaOAl2O3. The formation of the oxide layer prevented the spreading of liquid iron, leading to the increase of the contact angle. 相似文献
10.
The effect of MgO on the composition and properties of alite-sulphoaluminate cement clinker with commercial-grade raw materials such as limestone, clay, gypsum and fly ash as starting materials has been investigated in order to confirm results previously obtained with pure raw materials. The experiment results confirm that the addition of MgO at about 2-5% can improve the burnability of raw meal, promote the absorption of free lime and the formation of C3S and C4A3S¯. In addition, it is shown that this can also increase the strength development of the cement and shorten the setting time. When the content of MgO reaches about 8%, the strength of the cement decreases slightly and the setting time is extended. 相似文献