换能器结构参数对聚合物超声塑化黏弹生热的影响

为研究超声换能器结构参数对聚合物超声塑化过程黏弹性生热的影响，首先确定超声黏弹性生热系统的组成，进行纵振超声换能器结构设计；然后分析超声黏弹性生热过程及超声黏弹性生热原理；最后采用单一变量法分析超声换能器的主要结构参数对其纵振频率及工具头前端质点最大振幅的影响，将其实际输出的纵振激励加载于熔融聚合物，研究其结构参数对聚合物超声黏弹性生热过程及达到聚合物玻璃化转变温度所用时间的影响。结果表明，随纵振激励作用时间的增加，聚合物温度非线性升高；放大比对聚合物温度变化影响最大，前盖板厚度和工具头长度次之，影响最小的是变幅杆长度。     

油藏中分散非连续残余油膜的驱替机理分析

水驱后的残余油膜将贴于孔隙壁面，为壁面边界层流体，处于三相界面的包围和共同作用下。目前的调研结果显示，油膜的组成及力学特性沿孔壁方向上是变化的。在化学驱过程中油膜不仅受到驱油剂的驱替作用。还受驱油剂／油界面张力、油／固体界面张力及驱油剂／固体界面张力的阻碍作用。由于油膜组成、力学特性及相间作用的复杂性．以往对油膜驱替机理的研究都是从微观实验的角度对现象作观察和定性解释。本文根据水驱后残余油膜在油藏孔隙中存在的特点，提出了油膜驱替的简化模型。基于油膜驱替的微观实验，采用数值方法从定量的角度分别计算了不同黏弹性驱油剂在不同的驱油剂／原油界面张力作用下对残余油膜的驱替效率。考察了驱油剂的流变性、驱油剂／油界面张力、驱替速度等因素对驱替不同厚度油膜的影响规律。进一步探讨了驱油剂／原油界面特性和流变性在驱替残余油中的综合作用。研究结果表明，驱油剂对油膜的驱替始于驱油剂／油界面，要同时克服驱油剂／油界面约束力和油膜的屈服应力。降低界面张力、增强驱油剂的黏弹性、增加驱替速度，有利于提高驱替残余油膜的驱替效率。适当增加驱油刑的黏弹性可以放宽驱替薄油膜时对超低界面张力的要求。图13参9。     

Analysis and simulations of vibrations of a beam with a slider

A model for vibrations of a beam with a slider is derived, analysed and numerically simulated. It describes a viscoelastic beam that is clamped at one end to a vibrating device, while the other end moves between two stops attached to a slider. The contact is described by the normal compliance or by the Signorini conditions. The existence of weak solutions is established using the theory of set-valued pseudomonotone operators. The model is discretized using fourth-order spatial discretization, the solutions are numerically simulated and their results presented. The dynamics of the vibrations are depicted and so are the noise characteristics of the system.     

气泡在粘弹性液体中溶解的研究进展

在发泡塑料的制造过程中，均相气体－聚合物体系的形成直接影响了制品的物理机械性能，因此了解气泡在粘弹性液体中的溶解机理成为必然。本文讲述了气泡在流体中塌陷行为的研究进展。对Rayleigh对低粘度牛顿流体，Foqer和Goddand在无线量线性Maxwell模型的粘弹性体，Tanasawa和Tang用oldroyd三常数粘弹模型等科学家的研究行为做了概述，总结出影响此过程的复杂的影响因素，并指出进一步的研究方向。     

挠性胶管的阻尼减振机理初探

建立了挠性胶管阻尼耗能的简化模型。以此为基础分析了挠性胶管的阻尼耗能的一般规律,并得出了一些新的结论。     

Measuring and modeling the rheological data of diglycidylether of bisphenol‐A during polymerization for finite element analyses

Finite element analyses (FEA) of thermosets are often performed on the basis of rheological data for fully cured resin. For the FEA of thermosets during curing, a material model is established and a technique is demonstrated, which allows the rheological data of the linear viscoelastic material to be derived. As the moduli are sensitive to conversion, all measured properties are related to temperature and conversion. Therefore the basis for the rheological data has to be a suitable reaction kinetic. Based on the kinetics shear and compression properties are measured independently and modeled mathematically with the focus to gain a formulation, which is suitable for FEA. The considered time constants are in the range between one second and one month as these times are relevant for the investigated relaxation times. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1868–1872, 2003     

Application of Galerkin Method to Dynamical Behavior of Viscoelastic Timoshenko Beam with Finite Deformation

The motion equations governing the dynamical behavior of a viscoelasticTimoshenko beam with finite deformation are derived and simplified byGalerkin method. The viscoelastic material is assumed to obey thethree-dimensional fractional derivative constitutive relation. Thedynamical behaviors of the simplified systems with order 1 and order 2are numerically computed and compared by using the computational methodpresented by the authors. The dynamical behaviors of the systems areuniform qualitatively, but there is a little deviation quantitatively.And the truncated system with order 1 is safer than the one of order 2.It is also shown that the lower order system is reasonable. Theinfluences of the load parameter and the fractional derivative parameter(material parameter) on the deflection of the beam are consideredrespectively. The numerical methods in nonlinear dynamics, such as phasediagram, and Poincaré section, are applied to reveal dynamical behaviorsof the nonlinear viscoelastic Timoshenko beam. There are plenty ofdynamical behaviors, such as periodicity, bifurcation, quasi-periodicityand chaos in the dynamical system.     

约束层阻尼夹芯板动态特性分析

本文给出了新的建立约束层阻尼薄板动力学模型的方法。粘弹性材料的本构关系随温度和频率变化,难以对粘弹结构进行动特性分析及控制研究,本文采用GHM方法描述弹性材料的本构关系,将粘弹性材料的动力特性描述与工程上最常用的有限元分析结合起来,建立了悬臂约束层阻尼板的动力学模型,计算了约束层阻尼夹芯悬臂板的模态参数,计算结果同其它方法相比,精度高且更接近于实验结果,同时与ANSYS5.5及NASTRAN70.7的计算结果基本一致,表明本文给出的方法是准确可靠的。     

Thermally induced microstructural changes in cotton fibers: A free‐volume study

I measured positron lifetime in natural polymer–cotton fibers as a function of isochronal annealing temperature in the range 27–290°C. The variations in the positron results indicated structural changes occurring in the cotton fibers and determined the glass‐transition temperature as 80°C. Activation energies were measured separately for the crystalline and amorphous regions, indicating the versatility of the technique. These values were close to the O? H bond dissociation energy, suggesting O? H bond dissociation, the most probable process occurring under thermal treatment. As an extension of the positron results, the molecular weight of the cotton fibers was determined to be 1,200,000 based on free volume, which was within the range suggested for cotton. There seemed to be an indication that crosslinking changed the spiral structure of cotton fibers to the network type. However, this needs to be validated by other measurements. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3336–3345, 2002     

Viscoelastic Windows of Pressure-Sensitive Adhesives

A viscoelastic window (VW) concept has been proposed to identify different types of pressure-sensitive adhesives (PSA's). Such viscoelastic windows are constructed from the values of dynamic storage modulus: G' and dynamic loss modulus G' at frequencies of 10^-2 and 10² rad/sec. These frequencies are chosen because the range covers most of the time scales corresponding to the uses of PSA's at different application rates in performance tests. A four quadrant concept has also been recommended to categorize different types of PSA's based on the location of their VW's on the log-log cross plot of G' and G'. It was found that for most PSA's, the range of G' and G' at room temperature within these selected frequencies falls between 10³ and 10⁶ Pascals. The proposed four-quadrants (top-left hand quadrant of high G' and low G', top-right hand quadrant of high G' and high G', lower left hand quadrant of low G' and low G', and lower right-hand quadrant of low G' and high G') correspond respectively to (1) non-PSA or release coatings (2) high shear PSA's, (3) removable PSA's and medical PSA's and (4) quick and cold stick PSA's. It was also observed that the VW's of general purpose permanent PSA's occupy the central region which straddles part of the four quadrants.