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排序方式: 共有5737条查询结果,搜索用时 15 毫秒
1.
Paul J. Flory 《Polymer International》1985,17(2):96-102
The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters. 相似文献
2.
An efficient algorithm for the random packing of spheres can significantly save the cost of the preparation of an initial configuration often required in discrete element simulations. It is not trivial to generate such random packing at a large scale, particularly when spheres of various sizes and geometric domains of different shapes are present. Motivated by the idea of compression complemented by an efficient physical process to increase packing density, shaking, a new approach, termed compression algorithm, is proposed in this work to randomly fill any arbitrary polyhedral or cylindrical domains with spheres of various sizes. The algorithm features both simplicity and high efficiency. Tests show that it takes 181 s on a 1.4-GHz PC to complete the filling of a cylindrical domain with a total number of 26,787 spheres, achieving a packing density of 52.89%. 相似文献
3.
We have measured the thermal contact conductance of several demountable copper joints below 1 K. Joints were made by bolting together either two flat surfaces or a clamp around a rod. Surfaces were gold plated, and no intermediate materials were used. A linear dependence on temperature was seen. Most of the measured conductance values fell into a narrow range: 0.1-0.2 W K−1 at 1 K. Results in the literature for similar joints consist of predictions based on electrical resistance measurements using the Wiedemann-Franz law. There is little evidence of the validity of this law in the case of joints. Nevertheless, our results are in good agreement with the literature predictions, suggesting that such predictions are a reasonable approximation. 相似文献
4.
William F. Maloney 《Canadian Metallurgical Quarterly》2003,129(2):165-172
The satisfaction that a customer has with the construction product and construction services provided by a contractor has a direct influence on the customer’s willingness to select that contractor for future work. Labor and management working together have the opportunity to influence customer satisfaction. Activities at the contractor/craft worker level, the contractor/local union level, and the contractor association/local union level have the greatest potential to influence customer satisfaction. A precisely defined plan incorporating labor-management activities targeted at specific satisfaction factors will have the greatest likelihood of creating high customer satisfaction. 相似文献
5.
W.R. Jong T.H. Kuo S.W. Ho H.H. Chiu S.H. Peng 《International Communications in Heat and Mass Transfer》2007
Capillary phenomena was studied and discussed by the scholars about 200 years ago, but the progress was slow due to the limited equipment and manufacture precision of the microchannel. In recent years, because of the rapid development of MEMS and micromachining, many applications of the capillary flow is widely developing in some modern processes, such as underfilling of flip chip, flow in microfluidic chip or biochip, and a variety of other fields. 相似文献
6.
The present paper is devoted to the analysis of the contact problems with Coulomb friction and large deformation between two hyperelastic bodies. One approach to separate the material nonlinearity and contact nonlinearity is presented. The total Lagrangian formulation is adopted to describe the geometrically nonlinear behavior. Nondifferentiable contact potentials are regularized by means of the augmented Lagrangian method. Numerical examples are carried out in two cases: rigid-deformable contact and deformable-deformable contact with large slips. The numerical results prove that the proposed approach is robust and efficient concerning numerical stability. 相似文献
7.
This study is based on a theoretical and photoelastic static contact stress analysis, relevant to the design of the plastic tibial plateau in an orthopaedic knee prosthesis. It involves the review of existing theoretical analyses concerned with the contact mechanics of layered elastic systems and, where possible, the validation of any relevant findings using two dimensional photoelasticity. Significant findings include the identification of a general minimum recommendable design thickness for the plastic tibial plateau, the endorsement of using the Hertzian contact theory to predict contact stress levels in the tibial plateau of certain knee implants and the slight improvement in contact conditions in the plastic when the plateau is perfectly bonded to its supporting metal tray. 相似文献
8.
离子色谱技术在钻井现场的应用研究 总被引:1,自引:0,他引:1
将离子色谱技术(IC)应用于钻井现场的钻井液滤液分析,从而获取所钻井钻遇地层的可溶性矿物的性质、地层水的类型等资料信息。离子色谱技术在这一领域的应用尚属探索阶段,但通过现场两口井的试用已见到较好的应用效果,文章简介了该技术的应用前景及价值,如:确定油水界面的位置及指导钻井液的调配、确保井下安全等。这方面的论述,对分析化验仪器向井场转移实现多手段综合分析具有一定的促进作用。 相似文献
9.
David Arditi 《Canadian Metallurgical Quarterly》1985,111(1):1-14
Construction productivity has been on the decline in the last decade. The results are presented on a survey of the Engineering News‐Record 400 largest contractors to obtain their views on where productivity improvements would most help and to compare the trends with a similar survey carried out in 1979. Data were collected on the general company characteristics of the responding contractors, and on the contractors' opinions on potential areas for productivity improvement in the office and in the field. Findings indicate that immediate research should concentrate on improving marketing practices, planning and scheduling, labor‐management relations, site supervision, industrialized building systems, equipment policy and engineering design; and that governmental regulations have lost the immediate urgency attached to them in 1979.It is also recommended that similar surveys be conducted every 3 to 4 years to identify new trends and to steer research in the appropriate direction. 相似文献
10.
M. Muhr S. Pack S. Jaufer H. Lugschitz 《e & i Elektrotechnik und Informationstechnik》2006,123(12):537-543
New developments in diagnostic tools and systems are necessary for a reliable and economic evaluation of the condition of
equipment in power systems. In a research project a tool for the condition of contacts of centre break disconnector, which
is used under normal operation by the aid of a thermography measurement system, has been developed. In this paper, an overview
about the laboratory investigation of the temperature load behaviour and the environmental influence on-site for new and aged
disconnector contacts are given. A condition evaluation tool for contacts, which was the aim of the project, has been created.
The basic method for the evaluation is presented, and also two additional easements for a fast identification of suspect contacts
are presented. With this evaluation tool and the usage of a thermography based measuring system, a condition based maintenance
strategy can be applied, whereby an early detection of damages is possible and so power quality and reliability increase.
相似文献