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1.
Erik Zipperling Benedikt Dahlmann Markus Zdrallek Christian Derksen Stefan Eicker Heiko Serafin 《化学,工程师,技术》2021,93(4):624-631
Demands on production, distribution and consumption of electrical energy change fundamentally with the energy revolution. Energy purchasing costs for inflexible consumers are rising and proceeds of inflexible producers are sinking. Companies are able to reduce costs by marketing operational flexibility options. This article sets out the need of flexibility in the energy system and the new marketing options. Flexibility potentials within infrastructure plants of a chemical park are analyzed, evaluated regarding marketing and activated in the presented research project FlexChemistry. 相似文献
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Henrik Szentes 《Construction Management & Economics》2018,36(3):125-140
In recent years, scholars have shown a growing interest in combining control and flexibility when organizing and managing large construction projects, in contrast with the traditional focus on control. Prior research recognizes that there is a paradoxical tension between control and flexibility, meaning that, while both approaches make sense individually, they appear impossible to combine. Large construction projects are interorganizational, which means that tensions between interorganizational control/flexibility coexist with tensions between intraorganizational direction/empowerment, but the interplay and possible reinforcing cycles involving the two tensions have rarely been investigated in prior research. A multiple case study of four large construction projects with three rounds of interviews show how intraorganizational direction/empowerment can influence interorganizational control/flexibility and vice versa, and demonstrate both vicious and virtuous reinforcing cycles that involve the two types of tensions. Therefore, contributing to the project management and construction management literature, it is argued that employing a systemic approach when studying interorganizational projects is essential. A systemic paradox perspective can reveal interdependencies between tensions at different organizational interfaces, improve the understanding of how individuals in all managerial positions interplay, and explain how reinforcing cycles emerge and develop; this is important to recognize when organizing, staffing and managing large construction projects. 相似文献
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为有效解决东北电力产能过剩,促进风电、核电等清洁能源消纳问题,提升燃煤供热机组的灵活性,针对东北地区某热电厂,通过对热电解耦时间、电锅炉型式以及不同电锅炉容量配置对机组实际发电负荷的影响等灵活性改造关键技术进行研究,确定了最佳电锅炉容量,提出了电锅炉装设方案,并对改造前后机组的调峰能力和性能指标进行对比分析。研究表明:随着电锅炉容量增长,抵减电锅炉用电后机组实际发电负荷率显著降低,提升火电机组灵活性改造后,电厂调峰能力显著提升,考虑以全厂172 MW发电负荷运行,电厂调峰能力在采暖初末期增加了368 MW,采暖中期增加了528 MW;全厂供热标煤耗由39.7 kg/GJ降低至34.3 kg/GJ,降低了5.4 kg/GJ;经济效益显著,扣除电锅炉用电成本后1个采暖季的调峰辅助服务补贴收益为1.47亿元;同时,电锅炉投运后可实现电厂的上网电量接近零,为清洁能源就地消纳做出贡献。 相似文献
5.
Dr. Katie R. Witkin Dr. Nicholas R. Vance Colleen Caldwell Dr. Quinn Li Dr. Liping Yu Prof. M. Ashley Spies 《ChemMedChem》2020,15(4):376-384
Glutamate racemases (GR) are members of the family of bacterial enzymes known as cofactor-independent racemases and epimerases and catalyze the stereoinversion of glutamate. D-amino acids are universally important for the proper construction of viable bacterial cell walls, and thus have been repeatedly validated as attractive targets for novel antimicrobial drug design. Significant aspects of the mechanism of this challenging stereoinversion remain unknown. The current study employs a combination of MD and QM/MM computational approaches to show that the GR from H. pylori must proceed via a pre-activation step, which is dependent on the enzyme's flexibility. This mechanism is starkly different from previously proposed mechanisms. These findings have immediate pharmaceutical relevance, as the H. pylori GR enzyme is a very attractive allosteric drug target. The results presented in this study offer a distinctly novel understanding of how AstraZeneca's lead series of inhibitors cripple the H. pylori GR's native motions, via prevention of this critical chemical pre-activation step. Our experimental studies, using SPR, fluorescence and NMR WaterLOGSY, show that H. pylori GR is not inhibited by the uncompetitive mechanism originally put forward by Lundqvist et al.. The current study supports a deep connection between native enzyme motions and chemical reactivity, which has strong relevance to the field of allosteric drug discovery. 相似文献
6.
A novel batch plant for supercritical CO2 applications is proposed which is not equipped with expensive components, such as high‐pressure pumps, making it particularly suitable for bench‐scale use. For the first time, the use of a hanging scale is suggested to weigh the amount of CO2 required for the experiment and the use of the thermodynamics to reach the working conditions. The rig is able to cover different applications, e.g., aerogel drying, impregnation, and extraction, showing high flexibility. An approximate cost analysis has been performed considering as a reference a 150‐mL vessel. It has been calculated that both the setup and running costs are considerably lower than the common batch and semicontinuous rigs. 相似文献
7.
This study assesses the potential of energy flexibility of space heating and cooling for a typical household under different geographical conditions in Portugal. The proposed approach modifies the demand through the optimization of the thermostat settings using a genetic algorithm to reduce either operational costs or interaction with the grid. The results show that the used energy flexibility indicator expresses the available potential and that flexibility depends on several factors, namely: i) thermal inertia of the archetypical household; ii) the time of use electricity tariffs; iii) users’ comfort boundaries; and iv) the geographical location of the houses. 相似文献
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Natsuko Goda Kana Shimizu Yohta Kuwahara Takeshi Tenno Tamotsu Noguchi Takahisa Ikegami Motonori Ota Hidekazu Hiroaki 《International journal of molecular sciences》2015,16(7):15743-15760
Intrinsically disordered proteins (IDPs) that lack stable conformations and are highly flexible have attracted the attention of biologists. Therefore, the development of a systematic method to identify polypeptide regions that are unstructured in solution is important. We have designed an “indirect/reflected” detection system for evaluating the physicochemical properties of IDPs using nuclear magnetic resonance (NMR). This approach employs a “chimeric membrane protein”-based method using the thermostable membrane protein PH0471. This protein contains two domains, a transmembrane helical region and a C-terminal OB (oligonucleotide/oligosaccharide binding)-fold domain (named NfeDC domain), connected by a flexible linker. NMR signals of the OB-fold domain of detergent-solubilized PH0471 are observed because of the flexibility of the linker region. In this study, the linker region was substituted with target IDPs. Fifty-three candidates were selected using the prediction tool POODLE and 35 expression vectors were constructed. Subsequently, we obtained 15N-labeled chimeric PH0471 proteins with 25 IDPs as linkers. The NMR spectra allowed us to classify IDPs into three categories: flexible, moderately flexible, and inflexible. The inflexible IDPs contain membrane-associating or aggregation-prone sequences. This is the first attempt to use an indirect/reflected NMR method to evaluate IDPs and can verify the predictions derived from our computational tools. 相似文献
10.
《Ceramics International》2021,47(22):31329-31336
Traditional inorganic materials exhibit rigidity owing to the lack of polymer chains in polymer materials or atom slipping in metals. However, nanometerization has been recently proposed for the conversion of inorganic oxide materials into flexible materials. Herein, the flexible inorganic luminescent material, CaTiO3:0.2%Pr3+, was synthesized through electrospinning, and the macroscopic flexibility of pure inorganic CaTiO3:0.2%Pr3+ was achieved. The flexible membrane was characterized via X-ray diffraction, thermogravimetry, scanning electron microscopy (SEM), and photoluminescence analyses. The grain size was analyzed at various calcination temperatures via SEM, and the results suggested that the increase in the calcination temperature resulted in the growth of crystal grains. Studies have reported that the growth of crystal grains is beneficial for improving the luminescence performance; however, to obtain better flexibility, smaller crystal grains are required. This study provides an important reference for the design of flexible inorganic materials. 相似文献