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用于纳米微反应器的微乳液的相行为研究
引用本文:王金英,张景林,彭英健.用于纳米微反应器的微乳液的相行为研究[J].中北大学学报,2009,30(4):349-353.
作者姓名:王金英  张景林  彭英健
作者单位:王金英,张景林(北京理工大学,爆炸科学与技术国家重点实验室,北京,100081;中北大学,化工与环境学院,山西,太原,030051);彭英健(中北大学,化工与环境学院,山西,太原,030051) 
摘    要:W/O型微乳液以其独特的结构可以用来制备纳米粒子的微反应器.为了遴选一个适用于制备纳米粒子的微乳液体系,利用相图分别研究了失水山梨醇单油酸酯(Span80)和聚氧乙烯(20)失水山梨醇单油酸酯(Tween80)混合表面活性剂、助表面活性剂、油相烷烃、温度等对W/O型微乳液的形成及微乳区面积的影响.研究结果证明:m(Span80)/m(Tween80)质量比为10/2,正己醇为助表面活性剂,且混合表面活性剂与正己醇的质量比为2/1,正辛烷为油相,温度为40℃,是一个适合用于纳米微反应器的W/O型微乳液体系.

关 键 词:微乳液  纳米微反应器  相图

Study on the Phase Behavior of Microemulsion System as a Nano-Reactor
WANG Jin-ying,ZHANG Jing-lin,PENG Ying-jian.Study on the Phase Behavior of Microemulsion System as a Nano-Reactor[J].Journal of North University of China,2009,30(4):349-353.
Authors:WANG Jin-ying    ZHANG Jing-lin  PENG Ying-jian
Affiliation:1.State Key Laboratory of Explosion Science and Technology;Beijing Institute of Technology;Beijing 100081;China;2.School of Chemical Engineering and Environment;North University of China;Taiyuan 030051;China
Abstract:The water in oil microemulsion(W/O) is used as the nano-reactor for preparing nano-particles because of its unique structure.In order to screen a suitable microemulsion system for preparing nano-particles,the influencing factors including such as Span80,Tween80,co-surfactants,aliphatic hydrocarbons,temperature were researched by phase diagram.The testing results indicate that the suited W/O microemulsion should be formed as following:(1) the mass ratio of m(Span80)/m(Tween80) is 10/2;(2) n-hexyl alcohol as ...
Keywords:Span80  Tween80
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