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Microstructure and indentation mechanical properties of plasma sprayed nano-bimodal and conventional ZrO2–8wt%Y2O3 thermal barrier coatings
Authors:L Wang  Y Wang  XG Sun  JQ He  ZY Pan  CH Wang
Affiliation:1. Laboratory of Nano Surface Engineering, Department of Materials Science, School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, PR China;2. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
Abstract:The nanostructured agglomerated feedstock used for plasma spraying was obtained by the nanoparticle reconstituting technique. Nanostructured and conventional ZrO2–8wt%Y2O3 (8YSZ) thermal barrier coatings (TBCs) have been prepared by atmospheric plasma spraying (APS) on 45# steel substrates with the NiCrAlY as the bond-layer. The microstructure and phase composition of feedstocks and corresponding coatings were characterized. The top layer of nanostructured 8YSZ TBCs is denser and has fewer defects than that of conventional TBCs. The elastic modulus, micro-hardness and Vickers hardness of nanostructured 8YSZ TBCs exhibit bimodal distribution while the conventional 8YSZ exhibit mono-modal distribution. The elastic modulus and elastic recoverability were also obtained by the nanoindentation test. The results indicate that the elastic modulus of nanostructured 8YSZ coating is lower than that of conventional 8YSZ coating, but the nanostructured 8YSZ coating has higher elastic recoverability than that of the conventional 8YSZ coating. The prediction of the average elastic modulus was established by the mixture law and weibull distribution according to the fraction of phases with different molten characteristic.
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