DC conductivity study of polyaniline and poly(acrylonitrile-butadiene-styrene) blends |
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Authors: | Fernando H Cristovan Fernando R de Paula Sherlan G Lemos Adilson JA De Oliveira Ernesto C Pereira |
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Affiliation: | 1. Laboratório Interdisciplinar de Eletroquímica e Cerâmica, Departamento de Química, Universidade Federal de São Carlos, CP 676, 13560-970 São Carlos, SP, Brazil;2. Laboratório Supercondutividade e Magnetismo, Departamento de Física, Universidade Federal, de São Carlos, CP 676, 13560-970 São Carlos, SP, Brazil;3. Departamento de Química, Universidade Federal da Paraíba, C.P.: 5093, 58051-970 João Pessoa, PB, Brazil |
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Abstract: | In this study, conducting blends of poly(acrylonitrile-butadiene-styrene) and polyaniline doped with dodecylbenzene sulfonic acid were prepared by solution blending. In order to understand the electrical conduction mechanism of the samples, DC electrical conductivity measurements of the blends were carried out in the temperature range of 80–320 K. The experimental results fit well with Mott's model of three-dimensional variable range hopping conduction. The values of Mott's temperature, density of states at the Fermi energy, average hopping distance and barrier height for the composites were calculated and presented. |
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