Kinetics of Formation of a Platelet-Reinforced Ceramic Composite Prepared by the Directed Reaction of Zirconium with Boron Carbide

The kinetics of formation of a new class of ceramic composite material, zirconium diboride platelet-reinforced zirconium carbides, are discussed. These materials are prepared by the directed reaction of molten zirconium with boron carbide to form a ceramic material composed of zirconium carbide matrix containing a controlled amount of residual zirconium metal. Results from interrupted growth studies, differential thermal analysis, adiabatic reaction temperature calculations, and kinetic measurements have been used to study the kinetics of the process. The reaction is very fast and proceeds parabolic ally with time with a rate constant between 1.6 X 10^-2 and 3.9 X 10^-2 cm²/_s. The proposed mechanism suggests that when molten zirconium contacts boron carbide, the molten zirconium exothermically reacts with the boron carbide to form a boron-rich liquid. Further reaction is sustained by the continuous dissolution of the boron carbide as the boron-rich liquid is drawn into the boron carbide. The product is a zirconium carbiride/zirconium carbide/zirconium composite which homogenizes quickly at the reaction temperature to yield a uniform product microstructure throughout the composite. Two alternative rate-limiting steps are discussed and the implications of each are explored.