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| 丁酮气相催化氧化制丁二酮 | |
| 引用本文： | 谢海燕,尹笃林,银董红,伏再辉,李谦和. 丁酮气相催化氧化制丁二酮[J]. 精细化工中间体, 2000, 0(4) |
| 作者姓名： | 谢海燕 尹笃林 银董红 伏再辉 李谦和 |
| 作者单位： | 湖南师范大学精细催化合成研究所!湖南长沙410081 |
| 摘 要： | 研究了丁酮气相催化氧化制丁二酮的新技术。结果表明 :硅藻土作载体时 ,随着P2 O5 /V2 O5 比从 1 6升高到 4 4 ,丁二酮的选择性逐渐增加到 33%左右 ,从 4 4升高到5 6,丁二酮的选择性增加幅度较缓。五氧化二钒的含量从 5%增加到 1 5% ,转化率和选择性基本稳定。添加K2 O或Na2 O后 ,丁二酮的选择性上升 1 0 %左右 ,而乙酸的选择性下降。 |
| 关 键 词： | 丁酮 丁二酮 催化剂 氧化 |
Catalytic Oxidation of Butan-2-one to Diacetyl |
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| XIE Hai yan,YIN Du lin,YIN Dong hong,FU Zai hui,LI Qian he. Catalytic Oxidation of Butan-2-one to Diacetyl[J]. Fine Chemical Intermediates, 2000, 0(4) | |
| Authors: | XIE Hai yan YIN Du lin YIN Dong hong FU Zai hui LI Qian he |
| Abstract: | The selective vapor phase air oxidation of butan 2 one to Diacetyl (MEK) had been studied over vanadium phosphone oxide catalyst. It was presented that (1) with the increase of p/v atomic ratio from 1.6 to 4.4, the selectivity increase to about 33%, and from 4.4 to 5.6, the selectivity nearly ceased to increase. (2) The addition of K 2O or Na 2O brought out marked increase of the selectivity of MEK formation with the loss of catalytic activity and marked decrease of selectivity of HAc. The vanadium pentoxide content in the range 5%～15% over the siliceous earth carrier, didn't change the conversion and selectivity. |
| Keywords: | butan 2 one diacetyl catalyst oxidation |
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