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The physicochemical properties of the mixed solvent of 2-piperidineethanol,sulfolane and water
Authors:Shuo Xu  Yi-Wei Wang  Frederick D. Otto  Alan E. Mather
Abstract:The physicochemical properties of the mixed solvent of 2-piper-idineethanol (2-PE), sulfolane (TMS) and water were determined over a wide range of temperatures and compositions. The density, the viscosity and the dissociation constant, as well as the solubility of N2O in this mixed solvent were correlated as a function of temperature and composition over the entire experimental range. The models are useful not only for the ternary solvent system, but also for the binary solvent systems, such as 2-PE+H2O and TMS+H2O. From the regression, it has been found that the interaction of aqueous 2-PE solution and aqueous TMS solution is negligible.
Keywords:sulfolane  nitrous oxide  density  viscosity  solubility  dissociation constant
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