Promotion effect of Au on perovskite catalysts for the regeneration of diesel particulate filters |
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Authors: | N Russo D Fino G Saracco V Specchia |
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Affiliation: | aDepartment of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy |
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Abstract: | Four LaBO3 perovskite catalysts (B = Cr, Mn, Fe and Ni), also supporting 2% by weight of gold, were prepared via the so-called Solution Combustion Synthesis (SCS) method, and characterized by means of XRD, BET, FESEM-EDS, TEM, O2-TPD and CO-TPR analyses. The performance of these catalysts, in powder form, was evaluated towards the simultaneous oxidation of soot and CO. The 2 wt.% Au–LaNiO3 showed the best performance with a peak carbon combustion temperature of 431 °C and a half CO conversion of 156 °C. The same nano-structured catalyst, deposited by in situ SCS directly over a SiC filter and tested on real diesel exhaust gases, fully confirmed the encouraging results obtained with catalyst powder. |
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Keywords: | Diesel particulate Perovskite catalyst Catalytic combustion Gold catalyst |
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