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Crack-Tip Transformation Zones in Toughened Zirconia
Authors:David B. Marshall  Michael C. Shaw  Reinhold H. Dauskardt  Robert O. Ritchie  Michael J. Readey  Arthur H. Heuer
Affiliation:Rockwell International Science Center, Thousand Oaks, California 91360;Center for Advanced Materials, Lawrence Berkeley Laboratory, University of California, Berkeley, California 64720;Department of Materials Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106
Abstract:
Transformation zones surrounding cracks in several toughened magnesia-partially-stabilized zirconia ceramics are characterized by optical interference measurements of surface uplift and by Raman microprobe spectroscopy. The measurements demonstrate that the volume fraction of transformation is nonuniform within the zone and that the extent of the frontal zone is approximately the same as that of the wake. Results are used to evaluate the crack-tip shielding stress intensity factor and to compare with the measured fracture toughness.
Keywords:crack tip    partially stabilized zirconia    Raman spectroscopy    transformations    toughness
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