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Electrochemical formation of Sm-Co alloys by codeposition of Sm and Co in a molten LiCl-KCl-SmCl3-CoCl2 system
Authors:Takahisa Iida  Yasuhiko Ito
Affiliation:Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University Sakyo-ku, Kyoto 606-8501, Japan
Abstract:Electrocodeposition of Sm and Co on a Cu substrate was investigated in a molten LiCl-KCl-SmCl3 (0.5 mol.%)-CoCl2 (0.1 mol.%) system at 723 K. Phase of the deposited Sm-Co alloys could be controlled by electrolysis potential. SmCo3 was formed on a Cu substrate by potentiostatic electrolysis in the potential range of 0.20-0.90 V (vs. Li+/Li). Sm2Co17 was obtained in the potential range of 0.90-1.50 V.
Keywords:LiCl-KCl  Molten salt  Sm-Co alloy  SmCl3  CoCl2  Electrodeposition
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