Electrochemical formation of Sm-Co alloys by codeposition of Sm and Co in a molten LiCl-KCl-SmCl3-CoCl2 system |
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Authors: | Takahisa Iida Yasuhiko Ito |
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Affiliation: | Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University Sakyo-ku, Kyoto 606-8501, Japan |
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Abstract: | Electrocodeposition of Sm and Co on a Cu substrate was investigated in a molten LiCl-KCl-SmCl3 (0.5 mol.%)-CoCl2 (0.1 mol.%) system at 723 K. Phase of the deposited Sm-Co alloys could be controlled by electrolysis potential. SmCo3 was formed on a Cu substrate by potentiostatic electrolysis in the potential range of 0.20-0.90 V (vs. Li+/Li). Sm2Co17 was obtained in the potential range of 0.90-1.50 V. |
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Keywords: | LiCl-KCl Molten salt Sm-Co alloy SmCl3 CoCl2 Electrodeposition |
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