Synthesis and characterization of four-armed star mesogen-jacketed liquid crystal polymer |
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Authors: | Xingzhu Wang Guanqun Zhong Xiayu Wang |
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Affiliation: | Institute of Polymer Science, Xiangtan University, Xiangtan 411105, Hunan Province, People's Republic of China |
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Abstract: | The synthesis of four-armed star mesogen-jacketed liquid crystal polymer was achieved by atom transfer radical polymerization in chlorobenzene solution using pentaerythritol terakis(2-bromoisobutyrate) (PT-Br) as an initiator and CuBr/sparteine complex as a catalyst. The results show that the number average molecular weigh is creased linearly vs. monomer conversion, and that the polydispersities were quite narrow (<1.19), which is the character of controlled polymerization. The structure was experimentally confirmed by 1H NMR. The liquid-crystalline behavior of the four-armed star polymer was studied using DSC and POM. Only the polymer with a Mn,GPC beyond 3.68×104 g/mol formed a liquid crystalline phase which was quite stable with a high clearing point. |
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Keywords: | Mesogen-jacketed liquid crystal polymer Atom transfer radical polymerization Star-shaped polymer |
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