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Morphological characterization of reaction injection moulded (RIM) polyester-based polyurethanes
Authors:Israel D. Fridman  Edwin L. Thomas  Ly James Lee  Christopher W. Macosko
Affiliation:Polymer Science and Engineering Department, University of Massachusetts, Amherst, Massachusetts 01003, USA;Department of Chemical Engineering and Material Science, University of Minnesota, Minneapolis, Minnesota 55455, USA
Abstract:Characterization studies of reaction injection moulded (RIM) processed (in-situ polymerized) polyester-based segmented thermoplastic polyurethane have been performed utilizing various morphological techniques. The fast and exothermic urethane polymerization results in large temperature gradients in the mould which influence molecular weight and morphological structures. The present work is conducted to draw relationships between sample morphology and the processing conditions utilized to form the polymer.
Keywords:To whom correspondence should be addressed
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