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Numerical analysis of the combustion characteristics of graphitic hydrogen-chlorine synthesis combustor with different intake strategies
Affiliation:1. State Key Laboratory of Automotive Simulation and Control, Jilin University, Changchun 130025, China;2. College of Automotive Engineering, Jilin University, Changchun 130025, China
Abstract:This study investigates the effect of intake strategies on the combustion and flows characteristics of hydrogen-chlorine synthesis combustors via numerical methods. A crucial issue of hydrogen-chlorine synthesis combustor is to have a sufficiently low flame height and high conversion efficiency. In this study, the combustion performance of combustors equipped with the annular tube, plum nozzle, and porous-bullet nozzle has been thoroughly analyzed. The temperature distribution and gas flow are analyzed using the method of fluid-solid coupling, which indicates that the combustor with porous-bullet nozzle had the best gas distribution, the maximum HCl mole fraction at outlet is 97.24%, and the lowest flame height is 3.4 m, which is 27.15% lower than the combustor with the annular tube. Furthermore, the nozzle structure has a great influence on the fluid velocity in the recirculation zone of the combustor. Finally, the effect of hydrogen/chlorine equivalence ratio (?) and inlet volume flow rate were analyzed, and it can be concluded that with the increase of inlet volume flow, the high-temperature area inside the combustor gradually increases. As the equivalent ratio increases, the combustor outlet's mole fraction changes with a normal distribution trend. It is the most appropriate when the chlorine gas flow rate is 1,100 m3/h and ? = 1.05. The research can be applied to the field of high-purity hydrogen chlorine production, providing researchers with some solutions.
Keywords:Non-premixed combustion  Hydrogen chlorine production  Synthesis combustor  Flame height  Conversion efficiency
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