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背表面形貌对硅太阳电池效率的影响
作者姓名:郭爱娟  叶发敏  郭里辉  纪冬  冯仕猛
摘    要:Different processes are used on the back surface of silicon wafers to form cells falling into three groups:textured, planar, and sawed-off pyramid back surface.The characteristic parameters of the cells, ISC, VOC, FF, Pm, and Eff, are measured.All these parameters of the planar back surface cells are the best.The FF, Pm, and Eff of sawed-off pyramid back surface cells are superior to textured back surface cells, although ISC and VOC are lower.The parasitic resistance is analyzed to explain the higher FF of the sawed-off pyramid back surface cells.The cross-section scanning electron microscopy(SEM) pictures show the uniformity of the aluminum-silicon alloy, which has an important effect on the back surface recombination velocity and the ohmic contact.The measured value of the aluminum back surface field thickness in the SEM picture is in good agreement with the theoretical value deduced from the Al-Si phase diagram.It is shown in an external quantum efficiency(EQE) diagram that the planar back surface has the best response to a wavelength between 440 and 1000 nm and the sawed-off back surface has a better long wavelength response.

关 键 词:表面形貌  太阳能电池  硅片  挥发性有机化合物  扫描电子显微镜  表面复合速度  寄生电阻  波长响应
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