Effect of PBI-HFA surface treatments on Pd/PBI-HFA composite gas separation membranes

For pure hydrogen separation, palladium was deposited on surface-treated polybenzimidazole (PBI-HFA, 4,4′-(hexafluroisopropylidene)bis(benzoic acid)) via the vacuum electroless plating technique (VELP). Since the hydrophobic characteristics of the polymer surface restrict strong adhesion of Pd on it and cause the peel-off of Pd film, various surface treatments have been employed. To increase the number of Pd anchoring sites on the PBI-HFA surface, mechanical abrasion (polishing) was applied, and to increase the hydrophilicity of the PBI-HFA surface, wet-chemical and O₂ plasma treatment (dry etching) were used. The thickness and effective permeating area of the deposited Pd films on the PBI-HFA membranes were estimated to be in the range of 160–340 nm and 8.3 cm², respectively. Among the tested membranes, membranes with Pd layers deposited on O₂ plasma treated PBI-HFA surfaces had the most uniform microstructure and the least number of defects compared to the other membranes. Gas permeation experiments were performed as a function of temperature and pressure. The gases used in the permeation measurements were H₂, N₂, CO₂, and CO (99.9% purity). A Pd-O₂30 m membrane, fabricated by O₂ plasma surface treatment during 30 min, exhibited superior gas separation performance (H₂ permeability of 275.5 Barrer), and proved to be impermeable to carbon monoxide. Enhancement of H₂ permselectivity of Pd/PBI-HFA composite membrane treated by O₂ plasma shows promising hydrogen separation membrane.