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Development of a robust and efficient biogas processor for hydrogen production. Part 1: Modelling and simulation
Authors:YS Montenegro Camacho  S Bensaid  S Lorentzou  N Vlachos  G Pantoleontos  A Konstandopoulos  M Luneau  FC Meunier  N Guilhaume  Y Schuurman  E Werzner  A Herrmann  F Rau  H Krause  E Rezaei  A Ortona  S Gianella  A Khinsky  D Fino
Affiliation:1. Politecnico di Torino, Corso Duca Degli Abruzzi 24, Torino, 10129, Italy;2. Aerosol & Particle Technology Laboratory (CERTH-CPERI), 6 Th Km Charilaou – Thermis, PO BOX 60 361, 570 01, Thermi, Thessaloniki, Greece;3. Université de Lyon, Institut de Recherches sur La Catalyse et L''Environnement de Lyon, IRCELYON UMR5256 CNRS, 2 Avenue Albert Einstein, F-69626, Villeurbanne Cedex, France;4. Institute of Thermal Engineering, Technische Universität Bergakademie Freiberg, Gustav – Zeuner – Straße 7, 09596, Freiberg, Sachsen, Germany;5. ICIMSI, SUPSI, Galleria 2, CH-6928, Manno, Switzerland;6. Erbicol SA, Viale Pereda 21, CH6228, Balerna, Switzerland;7. Amiagus, Savanoriu Str. 290, LT-49473, Kaunas, Lithuania;8. Hysytech Srl, Strada Del Drosso, 33/18, Torino, Italy;9. Karlsruhe Institute of Technology, Engler-Bunte-Institute, Engler-Bunte-Ring 7, 76131, Karlsruhe, Germany
Abstract:The present work deals with the modelling and simulation of a biogas Demo-processor for green hydrogen production via Autothermal reforming (ATR) process aimed at covering a wide span of potential applications, from fuel cells feed up to the production of pure hydrogen. The biogas ATR unit is composed of a structured catalyst support close coupled to a wall-flow filter that retain soot particles that can be formed during the ATR reaction. Modelling and simulation (CFD and FEM) were carried out to select the innovative catalyst support with promising results for the fuel processor. 3D digital sample reconstruction was performed for the selection of the appropriate porous structures commercially available for the soot filtration and furthermore, 2D CFD analysis was also used to examine flow uniformity issues due to soot trap integration downstream to the ATR. Moreover, the inherent flexibility of the model performed allowed its application in the assessment of the Demonstration plant operating in real conditions. Besides, Aspen simulation has demonstrated that the ATR process is the most promising process to hydrogen production compared to other types of reforming process.
Keywords:Modelling  Green hydrogen production  Biogas  Catalysts  Auto-thermal reforming reactor  Wall-flow filter
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