| 氯苄双羰基化反应动力学 |
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| 引用本文： | 欧阳平凯,范伟平,张湜.氯苄双羰基化反应动力学[J].中国化学工程学报,2000,8(4):379-384. |
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| 作者姓名： | 欧阳平凯 范伟平 张湜 |
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| 作者单位： | CollegeofPharmaceuticeandLifeScience,NanjingUniversityofChemicalTechnology,Nanjing210（）09,China |
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| 摘 要： | It is a multi-phase-catalyzed reaction to produce calcium phenylpyruvate by double carbonylation of benzylchloride. Based on the analysis of the reaction mechanism, a kinetic model of the carbonylation reaction was obtained. The model was verified through experiments in which the diffusion effect was neglected with the appropriate operation manner. But it is inevitable that the carbonylation process is controlled by diffusion as the autoclave scaling up.
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| 关 键 词： | 氯苄 双羰基化 反应动力学 多相催化反应 苯基丙酮酸钙 制备 |
| 修稿时间： | |
Kinetics of the Double Carbonylation of Benzylchloride |
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| Ouyang Pingkai,FAN Weiping,ZHANG Shi.Kinetics of the Double Carbonylation of Benzylchloride[J].Chinese Journal of Chemical Engineering,2000,8(4):379-384. |
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| Authors: | Ouyang Pingkai FAN Weiping ZHANG Shi |
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| Affiliation: | College of Pharmaceutics and Life Science, Nanjing University of Chemical Technology, Nanjing 210009, China |
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| Abstract: | It is a multi-phase-catalyzed reaction to produce calcium phenylpyruvate by double carbonylation of benzylchloride. Based on the analysis of the reaction mechanism, a kinetic model of the carbonylation reaction was obtained. The model was verified through experiments in which the diffusion effect was neglected with the appropriate operation manner. But it is inevitable that the carbonylation process is controlled by diffusion as the autoclave scaling up. |
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| Keywords: | benzylchloride carbonylation kinetics |
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