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A correlation between crystal structure and catalytic activity in the solid solutions CdMoxW1−xO4 |
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| Authors: | Macro Daturi Laurent Savary Guylene Costentin Jean-Claude Lavalley |
| Affiliation: | Laboratoire de Catalyse et Spectrochimie, ISMRA, 6, bd du Maréchal Juin, 14050 Caen Cedex, France |
| Abstract: | Two CdMoxW1−xO4 solid solutions with the scheelite and the wolframite structures were synthesised via different techniques and their structures were determined from powder refinements. The limit of the reciprocal solubility of Mo in CdWO4 has been checked. Several compositions of the solid solutions have been tested in the catalytic mild oxidation of propane or propene and relations between the structures and the catalytic activity are proposed. |
| Keywords: | Crystal structure CdMoxW1−xO4 Catalytic activity Powder refinements Mild oxidation |
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