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The solubility of deuterium in lithium-lead alloys
Authors:C.H. Wu
Affiliation:Kernforschungsanlage Jülich GmbH, Institut für Chemie, PO Box 1913, 5170 Jülich, Association KFA-EURATOM, Fed. Rep. Germany
Abstract:The solubility of deuterium in lithium-lead alloys was measured as a function of temperature and atomic fraction of lithium, XLi. It was found that, at the atom fraction XLi = 0.78, corresponding to the composition “Li7Pb2”, the solubility in the solid phase is lower by a factor of a few hundred than that in the liquid phase. The solubility of deuterium in the Li-Pb system decreases drastically with decreasing XLi. At about XLi = 0.17, which corresponds to the eutectic “Li17Pb83”, the solubility is independent of temperature. The transition from exothermal to endothermal dissolution occurred at about XLi ? 0.17.
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