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Interface-related electrical properties of cadmium selenide films
Affiliation:1. Instituto de Pesquisas Energéticas e Nucleares, IPEN-CNEN/SP, São Paulo, SP 05508-000, Brazil;2. Universidade Federal do Rio Grande do Norte, UFRN, Natal, RN 59072-970, Brazil;1. School of Materials Science and Engineering, No. 49 Ai Min Road, Xin Cheng Qu, Inner Mongolia University of Technology, Hohhot, Inner Mongolia Autonomous Region 010051, PR China;2. Guangxi Key Laboratory of Information Material, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials, School of Material Science and Engineering, Guilin University of Electronic Technology, Guilin, 541004, PR China
Abstract:An experimental method for determining the depletion depth in thin films of cadmium selenide is used to measure simultaneous variation of conductivity and the space-charge region. The temperature dependence of the conductance reveals donor levels distributed about 0.10 eV and 0.50 eV. Total depletion of films a few thousand angstroms thick produced by oxygen adsorption occurs by exhaustion of the shallow donors. Following exposure to the atmosphere at room temperature, the film conductance decreases by two orders of magnitude when heated in vacuum above 70°C. The subsequent time dependence of the current is shown to follow an Elovich-type relation. This effect is interpreted as conversion of physically adsorbed oxygen to chemisorbed oxygen. The role of evaporated silicon oxide layers in the prevention of the conversion process is discussed. The instability in thin film transistor threshold voltage above 200°C is described in terms of an interface desorption model.
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