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含硫气井新型高效溶硫剂体系的研制及评价
引用本文:李丽,刘建仪,宋昭杰,刘从领,刘敬平. 含硫气井新型高效溶硫剂体系的研制及评价[J]. 应用化工, 2011, 40(11): 1905-1908
作者姓名:李丽  刘建仪  宋昭杰  刘从领  刘敬平
作者单位:1. 西南石油大学国家重点实验室,四川成都,610500
2. 中石油长庆油田分公司,陕西西安,710021
3. 江苏油田工程院,江苏扬州,225009
摘    要:
对溶硫剂二甲基二硫醚(DMDS)、二芳基二硫醚(DADS)进行复配,并加入催化剂PT,得到了去除气井开发中沉积的硫的有效配方。催化剂PT在DMDS-DADS-PT体系中的加量为15%,压力为0.10 MPa,磁力搅拌速率为420 r/min下,25℃时,硫在DMDS-DADS-PT体系中的溶解度为173.6%,溶硫时间为2.52 min;90℃时,硫在DMDS-DADS-PT体系中的溶解度为600.8%,溶硫时间为0.55 min。其性能优于美国SULFA-HITECH溶硫剂和加拿大DMDS-DMF-NaHS溶硫剂。

关 键 词:含硫气井  元素硫  硫沉积  溶硫剂  溶解度

Development and evaluation of new efficient sulfur solvent system in sulfur gas well
LI Li,LIU Jian-yi,SONG Zhao-jie,LIU Cong-ling,LIU Jing-ping. Development and evaluation of new efficient sulfur solvent system in sulfur gas well[J]. Applied chemical industry, 2011, 40(11): 1905-1908
Authors:LI Li  LIU Jian-yi  SONG Zhao-jie  LIU Cong-ling  LIU Jing-ping
Affiliation:LI Li1,LIU Jian-yi1,SONG Zhao-jie2,LIU Cong-ling3,LIU Jing-ping1(1.State Key Laboratory,Southwest University of Petroleum,Chengdu 610500,China,2.PetroChina Changqing Oilfield Company,Xi'an 710021,3.Engineering Institute of Jiangsu Oilfield,Yangzhou 225009,China)
Abstract:
The dimethyl dissulfide(DMDS) compounded with diarylethenes dissulfide(DADS)and catalyst PT was added to get better sulfur solvent formula,which was effective to elemental sulfur in sulfur gas well.When the dosage of PT in DMDS-DADS-PT was 15%,pressure was 0.10 MPa,stirring speed was 420 r/min,the experiment had the results that when temperature was 25 ℃,the solubility of DMDS-DADS-PT was 173.6%,with time of 2.52 min;when temperature was 90 ℃,the solubility of DMDS-DADS-PT was 600.3%,with time of 0.55 min.The performance of DMDS-DADS-PT was superior to sulfur solvents of SULFA-HITECH from America and DMDS-DMF-NaHS from Canada.
Keywords:sulfur gas well  elemental sulfur  sulfur-deposition  sulfur solvent  solubility  
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