| O3/H2O2去除选矿废水中丁基黄药的研究 |
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| 引用本文： | 彭然,张汉泉,张亚平,张婷.O3/H2O2去除选矿废水中丁基黄药的研究[J].金属矿山,2011,40(11):155. |
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| 作者姓名： | 彭然 张汉泉 张亚平 张婷 |
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| 作者单位： | 1.武汉工程大学环境与城市建设学院；2.集美大学生物工程学院 |
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| 基金项目： | 国家自然科学基金项目，福建省自然科学基金项目，福建省青年创新人才项目，厦门市杰出青年科技人才创新项目，集美大学创新团队基金项目，集美大学优秀骨干教师项目 |
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| 摘 要： | 用臭氧类高级氧化剂O3/H2O2对含有丁基黄药的模拟选矿废水进行了处理。考察了O3和H2O2的用量、溶液pH值、丁基黄药初始浓度、常见难免离子对废水CODCr去除效果的影响；并通过紫外-可见光谱和添加叔丁醇试验，探讨了O3/H2O2工艺去除丁基黄药的反应机理。结果表明：丁基黄药初始浓度为400 mg/L、pH=6.8的模拟废水1 000 mL，投加100 L/h 的O3和1 000 mg/L 的H2O2，反应2 h后CODCr的去除率可达60.25%；CO2-3和SO2-4有抑制废水中CODCr去除的作用，而Cu2+和Zn2+可以提高废水CODCr的去除率；O3/H2O2工艺去除废水CODCr反应遵循羟基自由基反应机制。
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| 关 键 词： | 选矿废水 丁基黄药 O3/H2O2 羟基自由基 |
Study on Removal of Butyl Xanthate in Floation Wastewater by O3/H2O2 |
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| Peng Ran,Zhang Hanquan,Zhang Yaping,Zhang Ting.Study on Removal of Butyl Xanthate in Floation Wastewater by O3/H2O2[J].Metal Mine,2011,40(11):155. |
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| Authors: | Peng Ran Zhang Hanquan Zhang Yaping Zhang Ting |
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| Affiliation: | 1.School of Environment and Civil Engineering，Wuhan Institute of Technology；2.School of biology Engineering，JiMei University; |
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| Abstract: | The stimulated flotation wastewater containing butyl xanthate was treated by O3/H2O2 process.Effects of O3 dosage，H2O2 dosage，pH value，initial solution concentration and common ions on wastewater CODCr removal were investigated.Reaction mechanism of removal of butyl xanthate by O3/H2O2 was studied by addition of tertiary butanol and using of UV-Vis absorption spectrum.The results showed that，CODCr removal rate can be reached 60.25% at 100 L/h of ozone dosage，1 000 mg/L of H2O2 dosage，pH 6.8 and 2 h of reaction time to 400 mg/L butyl xanthate.CODCrremoval is inhibited by introduction of CO2-3 and SO2-4.CODCrremoval rate is accelerated by introduction of Cu2+ and Zn2+.O3/H2O2process followed a hydroxyl radical type mechanism. |
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| Keywords: | Floation wastewater Butyl xanthate O3/H2O2" target="_blank">3/H2O2')" href="#">O3/H2O2 Hydroxyl radicals |
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