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石灰微观结构对铁水预处理脱硫的影响
引用本文:郝华强,任倩倩,张玉柱,郝素菊,蒋武锋,张卫攀.石灰微观结构对铁水预处理脱硫的影响[J].特殊钢,2016,37(2):16-18.
作者姓名:郝华强  任倩倩  张玉柱  郝素菊  蒋武锋  张卫攀
作者单位:1. 东北大学材料与冶金学院,沈阳 110004; 2. 华北理工大学冶金与能源学院,现代冶金技术教育部重点实验室,唐山 063009; 3. 钢铁研究总院先进钢铁流程及材料国家重点实验室,北京 100081;
基金项目:国家自然科学基金项目(51174075) 河北省自然科学基金项目(E2012209024)
摘    要:采用比表面积1.891~2.664 m2/g和平均孔径575.5~814.9 nm四种不同结构的活性石灰在高真空电弧熔炼旋淬一体机中进行铁水预处理脱硫实验。用扫描电子显微镜分析不同石灰样品表面形貌,并用全自动压汞仪测量石灰的比表面积和平均孔径。实验结果表明铁水脱硫率随着石灰平均孔径的增大而减小,随着比表面积增大而提高;最佳脱硫剂配比为1:50。可将铁水中硫含量从0.014%脱至0.001%。

关 键 词:铁水预处理  石灰  微观结构  脱硫率  脱硫剂配比  
收稿时间:2015-11-03

Effect of Microscopic Structure of Lime on Desulphurization of Pretreated Hot Metal
Hao Huaqiang,Ren Qianqian,Zhang Yuzhu,Hao Suju,Jiang Wufeng,Zhang Weipan.Effect of Microscopic Structure of Lime on Desulphurization of Pretreated Hot Metal[J].Special Steel,2016,37(2):16-18.
Authors:Hao Huaqiang  Ren Qianqian  Zhang Yuzhu  Hao Suju  Jiang Wufeng  Zhang Weipan
Affiliation:1. School of Materials and Metallurgy, Northeastern University, Shenyang 110004 ; 2. Key Laboratory of the Ministry of Education for Modem Metallurgy Technology, College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009; 3. State Key Laboratory of Advanced Steel Process and Products,Central Iron and Steel Research Institute, Beijing 100081
Abstract:The desulphurization test of pretreated hot metal using four different structure active limes with specific surface area 1.891-2.664 m2/g and average pore diameter 575.5-814.9 nm is carried out in a high vacuum arc melting spinning quenching machine. The surface morphology of different lime sample is analyzed by scanning electron microscope and the specific surface area and the average pore diameter of lime are measured by a fully automatic mercury injection apparatus. Experimental results show that with increasing the average hole diameter, the desulphurization rate of hot metal decreases and with increasing the specific surface area the desulphurization rate increases ; the optimum ratio of desulphurization agent is 1:50, in this case the sulphur content in hot metal decreases to 0.001 % from 0.014%.
Keywords:Hot Metal Pretreatment  Lime  Microscopic Structure  Desulphurization Rate  Ratio of Desulphurization Agent  
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