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Synthesis, formation and characterization of ZnTiO3 ceramics
Authors:Yee-Shin Chang  Yen-Hwei Chang  In-Gann Chen  Guo-Ju Chen  Yin-Lai Chai  Te-Hua Fang  Sean Wu
Affiliation:

a Department of Materials Science and Engineering, National Cheng Kung University, Tainan 701, Taiwan, ROC

b Department of Material Science and Engineering, I-Shou University, Kaohsiung 840, Taiwan, ROC

c Department of Resources Engineering, Dahan Institute of Technology, Hualien 971, Taiwan, ROC

d Department of Mechanical Engineering, Southern Taiwan University of Technology, Tainan 710, Taiwan, ROC

e Department of Electronics and Information Engineering, Tung-Fang Institute of Technology, Kaohsiung 821, Taiwan, ROC

Abstract:Zinc titanate (ZnTiO3) powders of perovskite structure were synthesized by conventional solid state reaction using metal oxides. Powders of ZnO and TiO2 in a molar ratio of 1:1 were mixed in a ball mill and then heated at temperatures from 700 to 1000 °C for various time periods in air. The crystallization temperature of ZnTiO3 powder was not, vert, similar820 °C, activation energy for crystallization was not, vert, similar327.14 kJ/mol and for grain growth was not, vert, similar48.84 kJ/mol. A transition point was observed when the electrical resistivity was measured versus temperature. Like some ferroelectric materials, a PTCR behavior above the transition temperature was observed with Curie temperature of not, vert, similar5 °C.
Keywords:A  Powders: solid state reaction  C  Dielectric properties  C  Electrical properties  D  Perovskites
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