| 6,6′-二硝基四氧化呋咱并[b,d,b′,d′]联苯的合成 |
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| 引用本文： | 陈博仁,廖支援.6,6′-二硝基四氧化呋咱并[b,d,b′,d′]联苯的合成[J].兵工学报,1992(2). |
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| 作者姓名： | 陈博仁 廖支援 |
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| 作者单位： | 北京理工大学
(陈博仁)，北京理工大学(廖支援) |
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| 摘 要： | 运用往芳环上引入氧化呋咱基团的方法合成了无氢化合物6,6′-二硝基四氧化呋咱并b,d,b′,d′]联苯(3),并对其部分性质做了报道。3,5,3′,5′-四叠氮基-2,4,6,2′,4′-五硝基联苯(1)经硝化后生成3,5,3′,5′-四叠氮基-2,4,6,2′,4′,6′-六硝基联苯(2),将(2)热解脱氮就得到题称化合物(3)。
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| 关 键 词： | 合成 苯并氧化呋咱 硝基化合物 联苯 |
SYNTHESIS OF 6,6'-DINITRO TETRAFUROXANO[b,d,b',d'] BIPHENYL |
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| Chen Boren Liao Zhiyuan.SYNTHESIS OF 6,6''''-DINITRO TETRAFUROXANO[b,d,b'''',d''''] BIPHENYL[J].Acta Armamentarii,1992(2). |
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| Authors: | Chen Boren Liao Zhiyuan |
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| Affiliation: | Beijing Institute of Technology |
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| Abstract: | A hydrogen-free compound 6,6'-dinitro tetrafuroxano (b, d, b' , d') biphenyl (3) was synthesized through the introduction of furoxano groups on the aromatic ring and some of its properties are reported. 3, 5, 3', 5'- tetraazido- 2, 4, 6, 2', 4', 5'- hexanitro biphenyl ( 2 ) was prepared through nitrating 3, 5, 3', 5'- tetraazido- 2, 4,6, 2', 4'-pentanitrobiphenyl, and then pyrolyzed to the title compound (3). |
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| Keywords: | synthesis benzofuroxan nitro compound biphenyl |
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