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Preparation and Characterization of Microporous Nano-Tungsten Trioxide and Its Photocatalytic Activity after Doping Rare Earth
引用本文:邹丽霞,钟秦,刘庆成. Preparation and Characterization of Microporous Nano-Tungsten Trioxide and Its Photocatalytic Activity after Doping Rare Earth[J]. 中国稀土学报(英文版), 2006, 24(1): 60-66. DOI: 10.1016/S1002-0721(06)60066-5
作者姓名:邹丽霞  钟秦  刘庆成
作者单位:Department of Applied Chemistry East China Technology Institute Fuzhou 344000 China College of Chemical Engineering Nanjing University of Science and Technology Nanjing 210094 China,College of Chemical Engineering Nanjing University of Science and Technology Nanjing 210094 China,Department of Applied Chemistry East China Technology Institute Fuzhou 344000 China
基金项目:Project supported by the Educational Science Foundation of Jiangxi in China ([2006]209) and Nuclear Resources and Environment Engineering Center of East China Technology Institute
摘    要:
Recently,heterogeneousphotocatalyticoxidation decompositionoforganiccontaminantshasbeenstud iedkeenlyinvariousfields.WO3isknownasamulti functionalmaterialapplicableforelectrochromicdis playdevice(ECD),semiconductorgassensor,cata lystetal.WO3,whosebandgapenergyhasbeenesti matedtobe2.5eV,hasthepotentialabilitytophoto catalyzeunderirradiationofvisiblelightofwavelength
关 键 词:稀土 掺杂 纳米三氧化钨 溶胶-凝胶法 过滤 微孔材料
文章编号:1002-0721(2006)01-0060-07
收稿时间:2005-02-26
修稿时间:2005-10-25

Preparation and Characterization of Microporous Nano-Tungsten Trioxide and Its Photocatalytic Activity after Doping Rare Earth
Lixia , Qin Zhong,Qingcheng Liu. Preparation and Characterization of Microporous Nano-Tungsten Trioxide and Its Photocatalytic Activity after Doping Rare Earth[J]. Journal of Rare Earths, 2006, 24(1): 60-66. DOI: 10.1016/S1002-0721(06)60066-5
Authors:Lixia    Qin Zhong  Qingcheng Liu
Affiliation:aDepartment of Applied Chemistry, East China Technology Institute, Fuzhou 344000, China;bCollege of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
Abstract:
Aqueous sols and gels of tungstic acid were prepared from Na2WO4 with protonated cation-exchange resin. Nano-tungsten oxide of a microporous lamella was synthesized by means of washing of WO3*2H2O with distilled water under ultrasonic wave agitation and centrifuging repeatedly, and the specific surface area tended to increase gradually with washing and centrifuging. The sample of centrifuged 7 h has more than 2 times highs specific surface area and more high photocatalytic activity . The mechanisms are also discussed.
Keywords:tungstic acid gels  washing and centrifuging  microporous  specific surface area  photocatalytic  rare earth oxides
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