Investigations on composition and morphology of electrochemical conversion layer/titanium dioxide deposit on stainless steel |
| |
Authors: | L Bamoulid F Benoît-Marquié A Guenbour M-T Maurette S El Hajjaji |
| |
Affiliation: | a Laboratoire d'Electrochimie-Corrosion, Faculté des sciences, Département de chimie, Av Ibn Batouta, BP 1014, Rabat, Morocco b Laboratoire des IMRCP, Groupe P.O.M., Université Paul Sabatier, 118 Route de Narbonne, F-31062 Toulouse, Cedex 4, France c Centre Inter-universitaire de Recherche et d'Ingénierie des Matériaux (CIRIMAT), Université Paul Sabatier, 118 Route de Narbonne, F-31062 Toulouse, Cedex 4, France |
| |
Abstract: | In this study, the formation and characterization of conversion coatings modified by a sol-gel TiO2 deposit were investigated as a way to develop a new photocatalyst for water and air depollution. The conversion coating, characterised by strong interfacial adhesion, high roughness and high surface area facilitates the sol-gel deposition of titania and enhances its adhesion to the substrate. The conversion treatment is carried out in an acid solution. Observation by Scanning Electron Microscopy (SEM) reveals a rough surface with pores and cavities. According to SIMS measurements, the thickness of the initial conversion layer is evaluated at about 1.5 μm. On this pre-functionalised support, the titanium dioxide was deposited by the sol-gel method. The roughness measurements coupled with SIMS analysis allowed a precise evaluation of the surface state of the final layers. The coating consists of two layers: a TiO2 outer layer and an inner layer containing iron chromium oxides. Characterization by X-ray diffraction (XRD) showed the existence of the TiO2 anatase structure as the main compound. |
| |
Keywords: | Conversion coating Sol-gel TiO2 Stainless steel |
本文献已被 ScienceDirect 等数据库收录! |
|