水热法合成钒钼磷系列多金属氧酸盐

较系统地论述了目前国内外已见报道的采用水热法合成技术制备钒钼磷系列多金属氧酸盐(以下简称VMoPO)的研究现状，归纳了各VMoPO的水热法合成条件，并从反应温度及反应物种等方面初步总结了几点合成规律；概述了VMoPO的组成中抗衡阳离子的种类—4种简单的有机含氮物和两种碱金属阳离子；根据各VMoPO中多阴离子的空间结构特点对其作了分类和较细致的结构描述，并展望了今后水热法合成VMoPO研究工作的主要内容和发展方向。

Studies on the Hydrothermal Synthesis of Vanadium Molybdophosphate Series Polyoxometallates

This essay reviewed the present investigation condition of hydrotheimal synthesis of vanadium molybdophosphate series polyoxometaUates (VMoPOs) that have been reported in China and foreign countries so far, Summed up the different kinds of synthesis conditions of these VMoPOs and summarized some of the pattern of synthesis with respect to reaction temperatures and reactants; Tlie different kinds of the counter cations in these compounds, four simple organic nitrogen containing compounds, and two alkaline metal cations were summerized generally; and the structures of the polyanions in these VMoPOs were discribed and classified in detail according to their space structural characters. The main scope and the developing direction of the future research work on this field are also predicted.